RSC - Faraday Discuss. latest articles

Nanoscale control of interfacial processes for latent fingerprint enhancement

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00053B, Paper

A. Robert Hillman, Rachel M Brown, Karl Scott Ryder, Claire Fullarton, Maximilian W. A. Skoda, Robert M Dalgliesh, Erik Watkins, Charlotte Beebee, Robert Barker, Andrew Glidle
Latent fingerprints on metal surfaces may be visualized by exploiting the insulating characteristics of the fingerprint deposit as a "mask" to direct electrodeposition of an electroactive polymer to the bare...
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Kinetic Limitations in Gas-Particle Reactions Arising from Slow Diffusion in Secondary Organic Aerosol

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00030C, Paper

Shouming Zhou, Manabu Shiraiwa, Robert McWhinney, Ulrich Poschl, Jonathan Abbatt
The potential for aerosol physical properties, such as phase, morphology and viscosity/diffusivity, to affect particle reactivity remains highly uncertain. We report here a study of the effect of bulk diffusivity...
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Influence of hot carriers on catalytic reaction; Pt nanoparticles on GaN substrates under light irradiation

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20133J, Paper

Sun Mi Kim, Dahee Park, Youngji Yuk, Sang Hoon Kim, Jeong Young Park
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Operando atomic structure and active sites of TiO2(110)-supported gold nanoparticles during carbon monoxide oxidation

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20157G, Paper

Marie-Claire Saint-Lager, Issam Laoufi, Aude Bailly
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The Microscopic Features of Heterogeneous Ice Nucleation May Affect the Macroscopic Morphology of Atmospheric Ice Crystals

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00059A, Paper

Stephen James Cox, Zamaan Raza, Shawn Kathmann, Ben Slater, A. Michaelides
It is surprisingly difficult to freeze water. Almost all ice that forms under "mild" conditions (temperatures > -40[degree]C) requires the presence of a nucleating agent - a solid particle that...
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Photophysics of fulvene under the non-resonant stark effect. Shaping the conical intersection seam

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20155D, Paper

Sergi Ruiz-Barragan, Lluis Blancafort
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Online and Offline Mass Spectrometric Study of the Impact of Oxidation and Ageing on Glyoxal Chemistry and Uptake onto Ammonium Sulfate Aerosols

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00051F, Paper

Jacqueline Hamilton, Maria Teresa Baeza Romero, Emanuela Finessi, Andrew R Rickard, Robert M Healy, Salvatore Peppe, Thomas J Adams, Mark J. S. Daniels, Stephen M Ball, Iain C. A. Goodall, Paul S Monks, Esther Borras Garcia, Amalia Munoz
Recent laboratory and modelling studies have shown that reactive uptake of low molecular weight [small alpha]-dicarbonyls such as glyoxal (GLY) by aerosols is a potentially significant source of secondary organic aerosol...
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A new unified model to calculate diameter-dependent partitioning between the vapour and multiple condensed phases in mixed inorganic-organic aerosol particles

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00047H, Paper

David Owen Topping, Mark Barley, Gordon McFiggins
A simple approach to calculate liquid-liquid phase separation has been developed based on the derivation of partitioning coefficients between multiple liquid phases and included in a framework used to partition...
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The magnitude and sources of uncertainty in global aerosol

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00043E, Paper

Ken Carslaw, Lindsay Lee, Carly Reddington, Graham Mann
Aerosol radiative forcing over the industrial period has remained the largest forcing uncertainty through all IPCC assessments since 1996. Despite the importance of this uncertainty for our understanding of past...
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Designs for molecular circuits that use electronic coherence

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD00009E, Paper

Francesca Fassioli, Daniel G. Oblinsky, Gregory D. Scholes
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Pt-group bimetallic nanocrystals with high-index facets as high performance electrocatalysts

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20146E, Paper

Na Tian, Jing Xiao, Zhi-You Zhou, Hai-Xia Liu, Yu-Jia Deng, Long Huang, Bin-Bin Xu, Shi-Gang Sun
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Ultrafast photo-initiated molecular quantum dynamics in the DNA dinucleotide d(ApG) revealed by broadband transient absorption spectroscopy

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD00003F, Paper

Mayra C. Stuhldreier, Friedrich Temps
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Active and passive control of zinc phthalocyanine photodynamics

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20156B, Paper

Divya Sharma, Annemarie Huijser, Janne Savolainen, Gerwin Steen, Jennifer L. Herek
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Ultrafast dual photoresponse of isolated biological chromophores: link to the photoinduced mode-specific non-adiabatic dynamics in proteins

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20150C, Paper

Anastasia V. Bochenkova, Lars H. Andersen
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How Do Organic Vapors Contribute to New-Particle Formation?

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00046J, Paper

Neil Donahue, Wayne Chuang, Ismael K. Ortega, Illona Riipinen, Francesco Riccobono, Siegfried Schobesberger, Josef Dommen, Markku Kulmala, Doug Worsnop , Hanna Vehkamaki
Highly oxidised organic vapors can effectively stabilize sulphuric acid in heteronuclear clusters and drive new-particle formation. We present quantum chemical calculations of cluster stability, showing that multifunctional species can stabilize...
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Aqueous aerosol SOA formation: Impact on aerosol physical properties

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00032J, Paper

Joseph L. Woo, Derek D. Kim, Allison N. Schwier, Ruizhi Li, Vivian Faye McNeill
Organic chemistry in aerosol water has recently been recognized as a potentially important source of secondary organic aerosol material (SOA). This SOA material may be surface-active, therefore potentially affecting aerosol...
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Morphology, dimension, and composition dependence of thermodynamically preferred atomic arrangements in Ag-Pt nanoalloys

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20138D, Paper

Lei Deng, Huiqiu Deng, Shifang Xiao, Jianfeng Tang, Wangyu Hu
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Regional and Global Impacts of Criegee Intermediates on Atmospheric Sulphuric Acid Concentrations and First Steps of Aerosol Formation

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00048F, Paper

Carl Percival, Oliver Welz, Arkke J. Eskola, John D Savee, David L Osborn, David Owen Topping, Doug Lowe, Steve Utembe, Asan Bacak, Gordon McFiggans, Mike Cooke, Alexander T Archibald, Michael Jenkin, R G Derwent, Ilona Riipinen, Daniel Mok, Edmond P. F. Lee, John Dyke, Craig A Taatjes, Dudley E Shallcross
Carbonyl oxides ("Criegee intermediates"), formed in the ozonolysis of alkenes, are key species in tropospheric oxidation of organic molecules and their decomposition provides a non-photolytic source of OH in the...
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Average chemical properties and potential formation pathways of highly oxidized organic aerosol

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00045A, Paper

Kelly E. Daumit, Sean H. Kessler, Jesse H. Kroll
Measurements of ambient organic aerosol indicate that a substantial fraction is highly oxidized and low in volatility, but this fraction is generally not reproduced well in either laboratory studies or...
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Morphologies of mixed organic/inorganic/aqueous aerosol droplets

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00049D, Paper

Mijung Song, Claudia Marcolli, Karl Ulrich Krieger, Daniel Lienhard, Thomas Peter
Despite major progress in the understanding of properties of tropospheric aerosol particles, it remains challenging to understand their physical state and morphology. To obtain more detailed knowledge of the phases,...
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Alumina support and Pdn cluster size effects on activity of Pdn for catalytic oxidation of CO

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20151A, Paper

Matthew D. Kane, F. Sloan Roberts, Scott L. Anderson
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Fabrication of complex model oxide catalysts: Mo oxide supported on Fe3O4(111)

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20134H, Paper

Chanut Bamroongwongdee, Michael Bowker, Albert F. Carley, Philip R. Davies, Robert J. Davies, Dyfan Edwards
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Organic Aerosol Formation Photoenhanced by the Formation of Secondary Photo-sensitizers in ageing Aerosols

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00044C, Paper

Kifle Zeleke Aregahegn, Barbara Noziere, Christian George
Secondary organic aerosols (SOA), which are produced by the transformations of volatile organic compounds in the atmosphere, play a central role in air quality, public health, visibility and climate but...
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Charge competition with oxygen molecules determines the growth of gold particles on doped CaO films

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20130A, Paper

Yi Cui, Kai Huang, Niklas Nilius, Hans-Joachim Freund
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Shape-selected bimetallic nanoparticle electrocatalysts: evolution of their atomic-scale structure, chemical composition, and electrochemical reactivity under various chemical environments

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20159G, Paper

Chunhua Cui, Mahdi Ahmadi, Farzad Behafarid, Lin Gan, Maximilian Neumann, Marc Heggen, Beatriz Roldan Cuenya, Peter Strasser
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The structure of AuPd nanoalloys anchored on spherical polyelectrolyte brushes determined by X-ray absorption spectroscopy

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD20132E, Paper

Julian Kaiser, Wojciech Szczerba, Heinrich Riesemeier, Uwe Reinholz, Martin Radtke, Martin Albrecht, Yan Lu, Matthias Ballauff
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Electrochemically assisted self-assembly of ordered and functionalized mesoporous silica films: impact of the electrode geometry and size on film formation and properties

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00021D, Paper

Gregoire Herzog, Emilie Sibottier, Mathieu Etienne, Alain Walcarius
Surfactant-templated mesoporous silica thin films can be deposited onto solid electrode surfaces by electrochemically assisted self-assembly (EASA). The method involves a cathodically triggered self-assembly of cationic surfactants (cetyltrimethyl ammonium bromide,...
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A Water Activity Based Model of Heterogeneous Ice Nucleation Kinetics for Freezing of Water and Aqueous Solution Droplets

Faraday Discuss., 2013, Accepted Manuscript
DOI: 10.1039/C3FD00035D, Paper

Daniel A Knopf, Peter A Alpert
Immersion freezing of water and aqueous solutions by particles acting as ice nuclei (IN) is a common process of heterogeneous ice nucleation which occurs in many environments, especially in the...
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CO and O overlayers on Pd nanocrystals supported on TiO2(110)

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20137B, Paper

Chi Ming Yim, Chi Lun Pang, David S. Humphrey, Christopher A. Muryn, Karina Schulte, Ruben Perez, Geoff Thornton
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Stability and migration barriers of small vanadium oxide clusters on the CeO2(111) surface studied by density functional theory

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD00012E, Paper

Joachim Paier, Thomas Kropp, Christopher Penschke, Joachim Sauer
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Helium droplets: a new route to nanoparticles

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20136D, Paper

Adrian Boatwright, Cheng Feng, Daniel Spence, Elspeth Latimer, Chris Binns, Andrew M. Ellis, Shengfu Yang
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Semi-hydrogenation of alkynes at single crystal, nanoparticle and biogenic nanoparticle surfaces: the role of defects in Lindlar-type catalysts and the origin of their selectivity

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C3FD00007A, Paper

G. A. Attard, J. A. Bennett, I. Mikheenko, P. Jenkins, S. Guan, L. E. Macaskie, J. Wood, A. J. Wain
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Catalyst nano-particle size dependence of the Fischer-Tropsch reaction

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20135F, Paper

Rutger A. van Santen, Albert J. Markvoort
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Preparation and structure of a single Au atom on the TiO2(110) surface: control of the Au-metal oxide surface interaction

Faraday Discuss., 2013, Advance Article
DOI: 10.1039/C2FD20131C, Paper

Kiyotaka Asakura, Satoru Takakusagi, Hiroko Ariga, Wang-Jae Chun, Shushi Suzuki, Yuichiro Koike, Hiromitsu Uehara, Kotaro Miyazaki, Yasuhiro Iwasawa
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