RSC - Org. Chem. Front. latest articleshttp://pubs.rsc.org/en/Journals/Journal/QORSC - Org. Chem. Front. latest articlesCopyright (c) The Royal Society of ChemistryTue, 19 Mar 2024 07:02:21 ZRSC - Org. Chem. Front. latest articleshttp://pubs.rsc.org/content/NewImages/rsc_publishing_logo.gifRSC - Org. Chem. Front. latest articleshttp://pubs.rsc.org/en/Journals/Journal/QOhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02133Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02133EPhotoinduced Cobalt Catalyzed Site Selective Alkylation of 2-Pyridones<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D3QO02133E, Research Article</div><div>Chenyue Li, Jin Li, Zibin Jiang, Yiwei Xu, Hujie Xiong, Fei-Long Liu, Tingting Liu, Fei Ye, Chenggui Wu<br/>Herein, a selective C3-and C6-alkylated reaction of 2-pyridone by direct C–H functionalization approach was used to access 2-pyridone derivatives. Under photocatalytic reaction conditions, alkyl halides or methanesulfonates were used as...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-19T00:00:00ZChenyue LiJin LiZibin JiangYiwei XuHujie XiongFei-Long LiuTingting LiuFei YeChenggui Wuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00220Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00220BOxidative Cyclization and Enzyme-free Deiodination of Thyroid Hormones<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00220B, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Julian Spils, Lucien D Caspers, Pim Puylaert, Boris Johannes Nachtsheim<br/>We introduce the first non-enzymatic deiodination of thyroid hormones from a so far unknown hypervalent iodaoxinium state. After developing oxidative processes for thyroxine(T4)-derived model cyclic diaryliodonium salts, we successfully produced...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-18T00:00:00ZJulian SpilsLucien D CaspersPim PuylaertBoris Johannes Nachtsheimhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00145Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00145ASynthesis of Chiral Sulfones via Nickel-Catalyzed Asymmetric Hydrogenation<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00145A, Research Article</div><div>Guiying Xiao, Xiaoxue Wu, Zhangtao Zhou, Guohua Hou<br/>An asymmetric hydrogenation of α,β-unsaturated sulfones was achieved based on the cheap transition metal nickel catalytic system. A series of chiral 3-alkyl-3-aryl sulfones and 3,3-diaryl sulfones were obtained in high...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-18T00:00:00ZGuiying XiaoXiaoxue WuZhangtao ZhouGuohua Houhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00320Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00320ASolvent dependent hierarchical dual helicity in a fused [4]carbohelicene/quinoline oligoamide foldamer<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00320A, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Rita Borges-Anastacio, Kevin Moreno, Eric Merlet, Thierry Buffeteau, Brice Kauffmann, Nathan D McClenaghan, Yann Ferrand, Céline Olivier<br/>Two classes of helical motif, namely [4]carbohelicene and aromatic oligoamide foldamer, were fused to form a hybrid molecular construct in which their helical axes are parallel. Depending on the solvent,...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-18T00:00:00ZRita Borges-AnastacioKevin MorenoEric MerletThierry BuffeteauBrice KauffmannNathan D McClenaghanYann FerrandCéline Olivierhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00169Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00169AConcise synthesis of pyrrolo[3,4-c]quinolines via a P(NMe2)3-catalyzed [4 + 2] annulation followed by a Zn/AcOH-mediated reduction-hydroamination-isomerization<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00169A, Research Article</div><div>Zhengyang Chen, Dan Xiong, Nengzhong Wang, Yufei Zhang, Hui Yao, Jinkun Zhang, Nianyu Huang, Kun Zou<br/>A P(NMe2)3-catalyzed [4 + 2] annulation of 2-amino-β-nitrostyrenes and β’-acetoxy allenoates followed by a Zn/AcOH-mediated reduction-hydroamination-isomerization has been developed. A range of tetrahydroquinolines and pyrrolo[3,4-c]quinolines bearing an all-carbon quaternary stereogenic...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-18T00:00:00ZZhengyang ChenDan XiongNengzhong WangYufei ZhangHui YaoJinkun ZhangNianyu HuangKun Zouhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00105Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00105BRu(II)-catalyzed cascade cis carbohalogenation and cyclization of alkyne-tethered cyclohexadienones for synthesizing tetrasubstituted alkenes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00105B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00105B, Research Article</div><div>Xiaoli Huang, Cui Yi, Ruji Xiong, Meiqi Bai, Yuhai Tang, Silong Xu, Yang Li<br/>A Ru(II)-catalyzed cis carbohalogenation and carbooxygenation cyclization of internal alkyne-tethered cyclohexadienones has been developed, which provided a novel approach to synthesize tetrasubstituted alkenes via aromatization and cross-couplings.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-12T00:00:00ZXiaoli HuangCui YiRuji XiongMeiqi BaiYuhai TangSilong XuYang Lihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00193Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00193AElectrochemical oxidative heterodifunctionalization of dehydroalanine: access to unnatural α,α-disubstituted amino esters<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00193A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00193A, Research Article</div><div>Hui Cao, Ruitao Wang, Qianqiu Zhang, Cuifen Lu, Yue Weng, Meng Gao<br/>A general, efficient, and mild Dha electrochemical modification strategy is reported, which enables a divergent route to various α,α-disubstituted amino esters <em>via</em> anodic cascade oxidation and nucleophilic attack.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-11T00:00:00ZHui CaoRuitao WangQianqiu ZhangCuifen LuYue WengMeng Gaohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02116Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02116EConvenient construction of tetraphenylethene (TPE) derivatives through Cu(II) mediated cascade dehydrogenation of EWG-activated diphenylmethane<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02116E" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02116E, Research Article</div><div>Qing Liu, Lihua Ye, Qing Wang, Siming Gong, Yongfa Xie, Zhangqiang Yan, Shusheng Yue, Zhenhong Wei, Hu Cai<br/>A sequential dehydrogenation reaction of activated diarylmethane derivatives mediated by copper(<small>II</small>) pivalate was developed, for preparation of electron-deficient tetraphenylethene (TPE) derivatives.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-11T00:00:00ZQing LiuLihua YeQing WangSiming GongYongfa XieZhangqiang YanShusheng YueZhenhong WeiHu Caihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00018Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00018HIodine(III)-mediated oxidative chlorination, bromination and iodination of chromone derivatives using alkyl halides as the solvent and halogen source<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00018H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00018H, Research Article</div><div>Yu-Ping Zhao, Jia-Lu Liao, Jiuzhong Huang, Shi-Kai Xiang, Chen-Fu Liu<br/>A protocol for iodine(<small>III</small>)-mediated oxidative chlorination, bromination and iodination of chromone derivatives has been developed using alkyl halide solvents such as CHCl<small><sub>3</sub></small>, CH<small><sub>2</sub></small>Br<small><sub>2</sub></small> and CH<small><sub>2</sub></small>I<small><sub>2</sub></small> as the halogen source.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-10T00:00:00ZYu-Ping ZhaoJia-Lu LiaoJiuzhong HuangShi-Kai XiangChen-Fu Liuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00020Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00020JSolvent involved synthesis of pyrrolidin-5-one-2-carboxamides via a sequential Ugi/olefination reaction<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00020J, Research Article</div><div>Na Chen, Tianyu Long, Han-Han Kong, Zheng-Wei Wu, Qing-Qing Yang, Nianyu Huang, Long Wang<br/>An unprecedented multi-component reaction with solvent participation and a novel conversion of sulfur ylides was developed via Ugi-5CR/pseudo-Wittig reaction to construct the pyrrolidin-5-one-2-carboxamides. This method features mild conditions, wide range...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-15T00:00:00ZNa ChenTianyu LongHan-Han KongZheng-Wei WuQing-Qing YangNianyu HuangLong Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00276Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00276HAccess to carbamates and o-aminobenzoates via oxidative car-bonylation of amines with CO and alcohols under rhodium/copper catalysis<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00276H, Research Article</div><div>Xiaoqi Chen, Xuyao Zhong, Lei Wang, Houyun Teng, Jingsheng Li, Shuai Chen, Rongjing Hu, Lei Yang<br/>An efficient Rh/Cu-based catalytic system for oxidative carbonylation of amines, alcohols and CO has been developed. A broad range of carbamates were prepared from primary amines and primary, secondary or...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-14T00:00:00ZXiaoqi ChenXuyao ZhongLei WangHouyun TengJingsheng LiShuai ChenRongjing HuLei Yanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00301Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00301BCatalytic Intermolecular Hydrofunctionalizations of Ynamides<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00301B, Review Article</div><div>Ying-Ying Zhao, Yu-Jing Jia, Yancheng Hu<br/>Ynamides are electron-rich alkynes with carbon-carbon triple bond directly attached to the nitrogen atom bearing an electron-withdrawing group. This unique structure renders diverse reactivites of ynamides in synthetic chemistry. Among...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-14T00:00:00ZYing-Ying ZhaoYu-Jing JiaYancheng Huhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00059Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00059ERecent progress in the synthesis of N-substituted arylamines by reductive cross-coupling of nitroarenes<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00059E, Review Article</div><div>Jing-Hao Qin, Yao Wang, Jun-Yao Ouyang, Min Liu, Xuan-Hui Ouyang<br/>Highly functionalized N-substituted arylamines are the core structural motifs of numerous biologically active molecules, agrochemicals, and functional materials. Classically, using arylamines as nitrogen sources via transition metal-catalyzed cross-coupling reactions and...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-13T00:00:00ZJing-Hao QinYao WangJun-Yao OuyangMin LiuXuan-Hui Ouyanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00041Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00041BPhotoinduced copper-catalyzed alkoxycarbonylation of alkyl fluorides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00041B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00041B, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Peng Yang, Yan-Hua Zhao, Xiao-Feng Wu<br/>A photoinduced copper-catalyzed alkoxycarbonylation of alkyl fluorides with phenols to synthesize various esters has been developed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-06T00:00:00ZPeng YangYan-Hua ZhaoXiao-Feng Wuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00165Fhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00165FEnantioselective Intramolecular Tandem Cyclization of o-Alkynylbenzamides: Generation of Enantioenriched CF3 containing Spiro-isoindolinone-indoles<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00165F, Research Article</div><div>Wenzhe Li, Min Li, Shuang Yang, Yinkun Yan, Xiao-Mei Zhang<br/>Enantioselective intramolecular tandem cyclization of dielectrophile-dinucleophile assembled o-alkynylbenzamides was realized using a chiral phosphoric acid as catalyst. A large variety of biologically important spiro-isoindolinone-indoles were achieved in moderate to good...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-12T00:00:00ZWenzhe LiMin LiShuang YangYinkun YanXiao-Mei Zhanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02096Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02096GThree-component approach to modular synthesis of tetra-substituted furans and pyrroles<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02096G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02096G, Research Article</div><div>Pei Zhang, Wenqing Ti, Tianfeng Gao, Jie Zhu, Aijun Lin, Shang Gao, Xuanyi Li, Hequan Yao<br/>A three-component one-pot reaction of TMSCF<small><sub>2</sub></small>Br, <em>p</em>-QMs and 1,3-dicarbonyl compounds and derivatives was developed. A series of densely functionalized tetra-substituted furans and pyrroles were constructed with excellent chemoselectivities.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-12T00:00:00ZPei ZhangWenqing TiTianfeng GaoJie ZhuAijun LinShang GaoXuanyi LiHequan Yaohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00137Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00137KAn iron-catalyzed nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides for accessing N-acyl azoxy molecules<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00137K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00137K, Research Article</div><div>Weimin Huang, Haobo Yan, Qianqian Wang, Jianhui Chen, Yanshu Luo, Yuanzhi Xia<br/>A nitrene transfer reaction of nitrosobenzenes with <em>N</em>-acyloxyamides using FeCl<small><sub>2</sub></small>·4H<small><sub>2</sub></small>O as a cheap and commercially available catalyst was developed for facile synthesis of <em>N</em>-acyl azoxy compounds with high functional-group compatibility.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-06T00:00:00ZWeimin HuangHaobo YanQianqian WangJianhui ChenYanshu LuoYuanzhi Xiahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00219Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00219ABN-Benzo[b]fluoranthenes: facile synthesis, characterization, and optoelectronic properties<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00219A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00219A, Research Article</div><div>Yuyi Wang, Siqi Liu, Peng Yang, Tao Shi, Jiawei Fan, Guijiang Zhou, Bochao Su<br/>A series of BN-benzo[<em>b</em>]fluoranthenes have been synthesized through straightforward N-directed borylative cyclization.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-05T00:00:00ZYuyi WangSiqi LiuPeng YangTao ShiJiawei FanGuijiang ZhouBochao Suhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02059Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02059BPalladium-catalyzed alkyne insertion and rearrangement reaction to synthesize oxindoles from o-iodonitroheteroarenes and alkynes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02059B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02059B, Research Article</div><div>Zhenjie Qi, Weijie Jia, Yang Chen, Jingbo Wang, Yafeng Zhao, Zhiqi Wang, Lin Huang, Baojing Ji, Shuai Liu, Dongfang Jiang<br/>A novel tandem reaction involving Pd(<small>II</small>)-catalyzed <em>ortho</em>-C–I bond functionalization, <em>O</em>-atom transfer, [1,2]-aryl shift and deoxygenation of <em>o</em>-iodonitroheteroarenes with alkynes for the synthesis of 3,3-disubstituted oxindoles is described.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-05T00:00:00ZZhenjie QiWeijie JiaYang ChenJingbo WangYafeng ZhaoZhiqi WangLin HuangBaojing JiShuai LiuDongfang Jianghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00086Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00086BPalladium-catalyzed siloxycarbonylation of alkenes to synthesize silyl esters<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00086B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00086B, Research Article</div><div>Fei Wu, Yi-Chuan Zhong, Bo Wang, Zhi-Hui Ren, Zheng-Hui Guan<br/>Synthesis of stable acyl intermediates and their transformation for the synthesis of carbonyl derivatives is highly desirable. We have developed a method for the synthesis of stable acyl intermediates, silyl esters, through siloxycarbonylation.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-04T00:00:00ZFei WuYi-Chuan ZhongBo WangZhi-Hui RenZheng-Hui Guanhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO90017Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO90017KOrganic Chemistry Frontiers welcomes the inaugural Early Career Advisory Board<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO90017K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1653-1661<br/><b>DOI</b>: 10.1039/D4QO90017K, Editorial</div><div><br/>Shengming Ma, Editor-in-Chief, introduces the inaugural <em>Organic Chemistry Frontiers</em> Early Career Advisory Board.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-04T00:00:00Zhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00092Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00092GSynthesis and immunogenicity evaluation of oligosaccharide epitopes for the development of a glycoconjugate vaccine against Streptococcus pneumoniae serotype 3<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00092G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00092G, Research Article</div><div>Xiaolin Ma, Jielin Zhao, Guirong Wang, Jiaxin Chen, Jiaqi Li, Zhen Huang, Guofeng Gu<br/>A preliminary structure–activity relationship study revealed the potential ST3 oligosaccharide antigenic epitope for anti-ST3 vaccine development.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-29T00:00:00ZXiaolin MaJielin ZhaoGuirong WangJiaxin ChenJiaqi LiZhen HuangGuofeng Guhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01973Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01973JMo-catalyzed cyclization of N-vinylindoles and skatoles: synthesis of dihydroindolo[1,2-c]-quinazolines and dihydroindolo[3,2-b]-indoles, and evaluation of their anticancer activities<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01973J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1668-1677<br/><b>DOI</b>: 10.1039/D3QO01973J, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Shannon Pecnard, Xinya Liu, Olivier Provot, Pascal Retailleau, Christine Tran, Abdallah Hamze<br/>Unveiling a Mo-catalyzed synthesis, unprecedented anticancer dihydroindolo[1,2-<em>c</em>]-quinazolines and dihydroindolo[3,2-<em>b</em>]-indoles were discovered from <em>N</em>-vinylazoles.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-08T00:00:00ZShannon PecnardXinya LiuOlivier ProvotPascal RetailleauChristine TranAbdallah Hamzehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02036Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02036CCatalytic asymmetric ring-opening of aminocyclopropanes with oxygen nucleophiles: access to chiral γ-amino acid derivatives<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02036C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1817-1823<br/><b>DOI</b>: 10.1039/D3QO02036C, Research Article</div><div>Ru-Lin Luo, Xiao-Bing Wang, Ming-Sheng Xie, Hai-Ming Guo<br/>Donor–acceptor aminocyclopropanes bearing both amino and carboxyl groups underwent catalytic asymmetric ring-opening reactions with diverse oxygen nucleophiles to afford chiral γ-oxygen-substituted γ-aminobutyric acid derivatives with good results.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-01T00:00:00ZRu-Lin LuoXiao-Bing WangMing-Sheng XieHai-Ming Guohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00017Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00017JRecent advances in metal-free catalytic enantioselective higher-order cycloadditions<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00017J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1824-1842<br/><b>DOI</b>: 10.1039/D4QO00017J, Review Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Bei Zhang, Jian Wang<br/>In this review, we briefly summarize the recent research progress in enantioselective higher-order cycloadditions, focusing on the preparation of medium-sized and multicyclic chiral molecules by metal-free catalysis.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-01T00:00:00ZBei ZhangJian Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01705Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01705B(o-CF3PhO)3P as a simple coupling reagent for direct amidation via activation of amines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01705B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1796-1803<br/><b>DOI</b>: 10.1039/D3QO01705B, Research Article</div><div>Lin Zhang, Nana Ma, Mei Wang, Wenchang Gou, Jie Tian, Qian Xu, Chong Zhao, Chun Li<br/>A new coupling reagent was applied in a simple and unprecedented manner for direct amidation. This approach enabled amide bond formation <em>via</em> activation of amines, which was verified by control experiments and DFT calculations.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-31T00:00:00ZLin ZhangNana MaMei WangWenchang GouJie TianQian XuChong ZhaoChun Lihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02129Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02129GRecent advances in nickel-catalyzed propargylic substitution<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02129G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1843-1857<br/><b>DOI</b>: 10.1039/D3QO02129G, Review Article</div><div>Feifei Tong, Dandan Hu, Chun Zhang, Jun-Qi Zhang, Hongjun Ren<br/>This work summarizes recent progress in nickel-catalyzed propargylic substitution reactions, categorizing them based on the diverse types of nucleophiles involved, with a specific focus on exploring asymmetric transformations.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-31T00:00:00ZFeifei TongDandan HuChun ZhangJun-Qi ZhangHongjun Renhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02134Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02134CSynthesis of α-heterofunctionalized carbonyl compounds via Brønsted acid-catalyzed oxygenative coupling of ynamides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02134C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1790-1795<br/><b>DOI</b>: 10.1039/D3QO02134C, Research Article</div><div>Tae-Woong Um, Hyun-Suk Yeom, Seunghoon Shin<br/>Brønsted acid-catalyzed addition of pyridine-<em>N</em>-oxides to ynamides forms <em>N</em>-enoxypyridinium ions that are functionally equivalent to α-carbonyl cations.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-31T00:00:00ZTae-Woong UmHyun-Suk YeomSeunghoon Shinhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00057Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00057AAsymmetric gold catalysis enabled by specially designed ligands<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00057A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1858-1895<br/><b>DOI</b>: 10.1039/D4QO00057A, Review Article</div><div>Amol B. Gade, Urvashi, Nitin T. Patil<br/>This review is planned to provide a comprehensive overview of the progress made in the design and development of chiral ligands for asymmetric gold catalysis.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-31T00:00:00ZAmol B. Gade UrvashiNitin T. Patilhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02100Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02100AVisible light-mediated ring opening and cyclization of aryl cyclopropanes: efficient synthesis of pyrrolo[1,2-a]quinoxalin-4(5H)-ones with antineoplastic activity<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02100A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1758-1764<br/><b>DOI</b>: 10.1039/D3QO02100A, Research Article</div><div>Jiabin Shen, Yong Yang, Chao Chen, Hao Xu, Chao Shen, Pengfei Zhang<br/>This study describes an efficient and green approach for the synthesis of potentially bioactive pyrrolo[1,2-<em>a</em>]quinoxalin-4(5<em>H</em>)-ones with appreciable functional group tolerance and a wide substrate scope.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-30T00:00:00ZJiabin ShenYong YangChao ChenHao XuChao ShenPengfei Zhanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02033Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02033ADearomative spiroannulation of indoles enabled by the diaza-[1,2]-Wittig rearrangement<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02033A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1685-1691<br/><b>DOI</b>: 10.1039/D3QO02033A, Research Article</div><div>Can Luo, Chun-Yan Guan, Zhen-Yu Li, Beiling Gao, Guang-Jian Mei<br/>Reported herein is the first diaza-[1,2]-Wittig rearrangement-enabled dearomative spiroannulation reaction of indoles. This protocol features metal-free conditions, a redox-neutral process, a broad substrate scope, and a good yield.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-30T00:00:00ZCan LuoChun-Yan GuanZhen-Yu LiBeiling GaoGuang-Jian Meihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01967Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01967EKoilodenoids A–G, immunosuppressive spiro dimers of diterpenoids from Koilodepas hainanense: structural elucidation and biomimetic transformation<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01967E" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1692-1699<br/><b>DOI</b>: 10.1039/D3QO01967E, Research Article</div><div>Yu Ren, Cheng-Yu Zheng, Jia-Ying Yao, Shi-Jun He, Yao-Yue Fan, Jian-Min Yue<br/>Seven new and immunosuppressive dimeric diterpenoids were elucidated. Compound <strong>1</strong> possesses a new carbon skeleton. The biomimetic transformation of <strong>2</strong> into <strong>1</strong> was achieved under mild, as well as peroxide- and metal-free conditions.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-30T00:00:00ZYu RenCheng-Yu ZhengJia-Ying YaoShi-Jun HeYao-Yue FanJian-Min Yuehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02000Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02000BNovel A-seco-nortriterpenoids from Ganoderma cochlear inhibiting Tau pathology by activating AMPK-ULK1-mediated autophagy<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02000B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1765-1774<br/><b>DOI</b>: 10.1039/D3QO02000B, Research Article</div><div>Rong-Can Luo, Yi Luo, Da-Shuang Fang, Yong-Gang Yao, Ming-Hua Qiu, Xing-Rong Peng<br/>Ten structurally diverse A-seco-nortriterpenoids were isolated from the fruiting bodies of <em>Ganoderma cochlear</em>. Compounds <strong>1–4</strong> significantly inhibited tau pathology by inducing autophagy mediated by AMPK-ULK1 pathway.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-30T00:00:00ZRong-Can LuoYi LuoDa-Shuang FangYong-Gang YaoMing-Hua QiuXing-Rong Penghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02076Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02076BEfficient stereoselective synthesis of aryl lactones using engineered ketoreductase ChKRED20 from Chryseobacterium sp. CA49<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02076B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1804-1810<br/><b>DOI</b>: 10.1039/D3QO02076B, Research Article</div><div>Mingliang Shi, Rude Lin, Yuan Yu, Yao Yao, Xinyue Fan, Kun Li, Zhongliu Wu, Xiaoqi Yu, Yan Liu, Na Wang<br/>WT <em>Ch</em>KRED20 which exhibits no activity towards γ,δ-keto esters was redesigned for reducing bulky keto esters to the corresponding lactones.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-29T00:00:00ZMingliang ShiRude LinYuan YuYao YaoXinyue FanKun LiZhongliu WuXiaoqi YuYan LiuNa Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01934Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01934AIron-catalyzed carboamination of vinylarenes with alkanes and nitrogen nucleophiles<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01934A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1742-1747<br/><b>DOI</b>: 10.1039/D3QO01934A, Research Article</div><div>Fengxiang Zhu, Jianxin Xue<br/>Carboamination of alkenes is rapidly emerging as an essential strategy for synthesizing complex nitrogen-containing compounds.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-29T00:00:00ZFengxiang ZhuJianxin Xuehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02079Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02079GHydrogen bond-promoted regio- and stereoselective synthesis of isoindoline derivatives through Pd-catalyzed isocyanide insertion reaction involving aziridines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02079G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1775-1781<br/><b>DOI</b>: 10.1039/D3QO02079G, Research Article</div><div>Shuang Zheng, Hao-Jie Fan, Shan-Shan Liu, Yang Xu, Zhi-Wen Zhao, Han-Han Kong, Ping He, Long Wang, Zhi-Lin Ren<br/>We have successfully demonstrated an efficient and practical Pd-catalyzed reaction between aziridine and isocyanide, leading to the synthesis of isoindoline derivatives in moderate to good yields.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-29T00:00:00ZShuang ZhengHao-Jie FanShan-Shan LiuYang XuZhi-Wen ZhaoHan-Han KongPing HeLong WangZhi-Lin Renhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01946Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01946BPd-catalyzed double Heck and Heck–Suzuki cascade reaction of N-(o-bromo aryl) CF3-acrylamides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01946B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1736-1741<br/><b>DOI</b>: 10.1039/D3QO01946B, Research Article</div><div>Ruchi Sharma, Naveen Sihag, Hemaang Bhartiya, Shivangi Saini, Ashish Kumar, M. Ramu Yadav<br/>A double Heck and Heck–Suzuki cascade approach using Pd catalyst yields trifluoromethyl-tethered 3,3-disubstituted oxindoles from <em>N</em>-(<em>o</em>-bromoaryl) trifluoromethyl acrylamide with alkenes/phenylboronic acids.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-26T00:00:00ZRuchi SharmaNaveen SihagHemaang BhartiyaShivangi SainiAshish KumarM. Ramu Yadavhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01970Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01970EDFT investigation of Cu(I)-catalyzed addition of 1,4-pentadiene to acetophenone: mechanism and selectivity for the synthesis of a chiral tertiary alcohol with a 1,3-diene unit<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01970E" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1748-1757<br/><b>DOI</b>: 10.1039/D3QO01970E, Research Article</div><div>Jihong Xu, Yiying Yang, Chengbu Liu, Dongju Zhang<br/>DFT calculations show a clear understanding of the reaction mechanism and the origin of selectivity in the chiral phosphoric acid ligand-controlled Cu(<small>I</small>)-catalyzed addition of 1,4-pentadiene to acetophenone.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-26T00:00:00ZJihong XuYiying YangChengbu LiuDongju Zhanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02004Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02004EAccess to chiral β-amino sulfones from acrylamides and sulfur dioxide by iron catalysis<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02004E" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1678-1684<br/><b>DOI</b>: 10.1039/D3QO02004E, Research Article</div><div>Liping Luo, Xuemei Zhang, Chunxi Huang, Zhong Lian<br/>This method allows for the enantioselective synthesis of β-azide sulfones via iron-catalyzed vicinal azide-sulfonylation of acrylamides. It makes the first instance of achieving asymmetric construction through iron catalysis with SO<small><sub>2</sub></small> insertion.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-25T00:00:00ZLiping LuoXuemei ZhangChunxi HuangZhong Lianhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01917Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01917ADidymorenloids A and B, two polycyclic cyclopenta[b]fluorene-type alkaloids with anti-hepatoma activity from the mangrove endophytic fungus Didymella sp. CYSK-4<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01917A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1706-1712<br/><b>DOI</b>: 10.1039/D3QO01917A, Research Article</div><div>Yan Chen, Wencong Yang, Ge Zhu, Guisheng Wang, Tao Chen, Hang Li, Jie Yuan, Zhigang She<br/>Molecular networking guidance lead to the isolation of a new cyclopenta[<em>b</em>]fluorene-type alkaloid didymorenloid A (<strong>1</strong>), containing an unprecedented 6/5/6/5/13(6)/5/5/5-fused ring system, from the mangrove endophytic fungus <em>Didymella</em> sp. CYSK-4.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-25T00:00:00ZYan ChenWencong YangGe ZhuGuisheng WangTao ChenHang LiJie YuanZhigang Shehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02071Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02071ARu(II)-catalyzed regioselective [4 + 1] redox-neutral spirocyclization of aryl amidines with diazopyrazolones: direct access to spiro[indole-3,4′-pyrazol]-5′-ones<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02071A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1811-1816<br/><b>DOI</b>: 10.1039/D3QO02071A, Research Article</div><div>Bo Cui, Jian Shen, Yadong Feng, Shenghui Lin, Xiuling Cui<br/>An efficient protocol to construct spiro[indole-3,4′-pyrazol]-5′-ones <em>via</em> ruthenium(<small>II</small>)-catalyzed selective C–H bond activation/[4 + 1] spirocyclization starting from easily available <em>N</em>-aryl amidines and diazopyrazolones has been developed.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-25T00:00:00ZBo CuiJian ShenYadong FengShenghui LinXiuling Cuihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02007Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02007JTransition-metal-catalyzed straightforward synthesis of N-trifluoromethyl indoles from 2-alkynylaryl isothiocyanates or 2-alkynylanilines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02007J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1720-1728<br/><b>DOI</b>: 10.1039/D3QO02007J, Research Article</div><div>Jianquan Hong, Chongbin Wei, Ruilong Feng, Kui Zhao, Yi Zhu, Chunxiang Li, Xifei Chen, Xinxin Gong, Dejing Yin, Changge Zheng<br/>Two new cascade approaches for <em>N</em>-CF<small><sub>3</sub></small> indoles <em>via</em> transition-metal-catalyzed reactions from 2-alkynylaryl isothiocyanates or 2-alkynylanilines have been demonstrated, featuring mild conditions, a broad substrate scope and moderate to high yields.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-25T00:00:00ZJianquan HongChongbin WeiRuilong FengKui ZhaoYi ZhuChunxiang LiXifei ChenXinxin GongDejing YinChangge Zhenghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02005Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02005CCooperative catalysis of carbenes and Lewis acids for the highly enantioselective synthesis of dihydroquinolones via in situ generation of aza-ortho-quinone methide and enolate intermediates<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02005C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1713-1719<br/><b>DOI</b>: 10.1039/D3QO02005C, Research Article</div><div>Zhiying Li, Zhenhong Wu, Huan Gong, Xinyi Xu, Jianfeng Xu, Xingkuan Chen<br/>An efficient protocol for the highly enantioselective synthesis of dihydroquinolones was developed <em>via</em> NHC-catalyzed [4 + 2] annulation between <em>in situ</em> generated aza-<em>ortho</em>-quinone methide and enolate intermediates.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-24T00:00:00ZZhiying LiZhenhong WuHuan GongXinyi XuJianfeng XuXingkuan Chenhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01979Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01979AOrganocatalyzed diastereoselective cyclization of β-alkyl nitroolefins with alkylidene malononitriles: new approach to azetidine nitrones and isoxazoles<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01979A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1782-1789<br/><b>DOI</b>: 10.1039/D3QO01979A, Research Article</div><div>Shikha S. Rathor, Ashvani K. Patel, Sampak Samanta<br/>An organocatalytic domino reaction of β-alkyl nitroolefins with alkylidene malononitriles to give azetidine nitrones with good diastereoselectivities is reported. The <em>in situ</em>-generated nitrones were transmuted into isoxazoles catalyzed by acid.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-23T00:00:00ZShikha S. RathorAshvani K. PatelSampak Samantahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01822Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01822AIron-catalyzed fragmentation-alkynylation, -alkenylation and -alkylation cascade enabled by photoinduced ligand-to-metal charge transfer<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01822A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1729-1735<br/><b>DOI</b>: 10.1039/D3QO01822A, Research Article</div><div>Yining Zhu, Han Gao, Jia-Lin Tu, Chao Yang, Lin Guo, Yating Zhao, Wujiong Xia<br/>An iron-catalyzed fragmentation alkynylation, alkenylation and alkylation enabled by photoinduced ligand-to-metal charge transfer (LMCT)processis herein reported.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-20T00:00:00ZYining ZhuHan GaoJia-Lin TuChao YangLin GuoYating ZhaoWujiong Xiahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02040Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02040APolyenolate-mediated reaction cascade initiated by higher-order-cycloaddition for the construction of polycarbocyclic scaffolds<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02040A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1700-1705<br/><b>DOI</b>: 10.1039/D3QO02040A, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Adam Cieśliński, Anna Skrzyńska, Artur Przydacz, Łukasz Albrecht<br/>Polyenolate activation constitutes a powerful strategy, enabling the formation of higherenes. Alkylidenemalononitriles derived from indene-2-carbaldehydes upon deprotonation participate in a cascade involving [10 + 2]-cycloaddition followed by Michael addition and aldol condensation.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-19T00:00:00ZAdam CieślińskiAnna SkrzyńskaArtur PrzydaczŁukasz Albrechthttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01684Fhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01684FAn electrochemical multicomponent cascade annulation and functionalization reaction to enable C(sp3)–H trifluoromethylation<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01684F" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1662-1667<br/><b>DOI</b>: 10.1039/D3QO01684F, Research Article</div><div>Yuxin Ding, Hao Zhang, Dingyuan Lou, Wenkai Huang, Yuan Shi, Hongmei Luo, Changjun Zhang, Yuanyuan Xie<br/>Herein, we describe a novel electrochemistry facilitated one-pot multicomponent cascade annulation and bi-functionalization reaction that enables the efficient synthesis of highly functionalized 3,4-dihydroquinazolinones, realising indirect C(sp<small><sup>3</sup></small>)–H trifluoromethylation of aromatic ketones.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2023-12-22T00:00:00ZYuxin DingHao ZhangDingyuan LouWenkai HuangYuan ShiHongmei LuoChangjun ZhangYuanyuan Xiehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00248Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00248BNaphthyridine-2NO, a new C2-symmetric rigid tetradentate bimetallic ligand and its application in asymmetric Friedel-Crafts alkylation<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00248B, Research Article</div><div>Xiong-Li Liu, Pan Hu, Ke-Lan Xu, Xi-Rui Wang, Zi-Yue Chen, Wen-Hui Zhang, Ying Zhou, Wenjing Zhang<br/>The development of dinuclear metal complexes as catalysts in asymmetric catalysis is in great demand but remains a particularly challenging goal. Herein, we rationally designed and developed a series of...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-11T00:00:00ZXiong-Li LiuPan HuKe-Lan XuXi-Rui WangZi-Yue ChenWen-Hui ZhangYing ZhouWenjing Zhanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00085Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00085DSelective Cross-Coupling of α,β-Unsaturated Nitriles with Aldehydes or Alcohols by Hydrogen Transfer Catalysis towards β-Ketonitriles and Glutaronitriles<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00085D, Research Article</div><div>Shi-Qi Zhang, Ji-Bao Xia<br/>The β-ketonitriles and glutaronitriles are both valuable compounds in chemical and pharmaceutical industry. We reported here a novel ruthenium-catalyzed selective cross-coupling of α,β-unsaturated nitriles with aldehydes or alcohols towards β-ketonitriles...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-11T00:00:00ZShi-Qi ZhangJi-Bao Xiahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00049Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00049HCopper-catalyzed selective construction of vinyl sulfones employing TosMIC as a C1 synthon and sulfone source<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00049H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00049H, Research Article</div><div>Qun Cai, Meng-Jie Si, Xin-Ru Shi, Meng Liao, Fa-Chuang Liu, Min Wang, Ke-Xin Li, Yong-Ting Chen, An-Xin Wu<br/>A novel strategy for the selective synthesis of (<em>E</em>)-vinyl sulfone derivatives from <em>p</em>-tosylmethyl isocyanide (TosMIC) and <em>ortho</em>-substituted benzaldehydes has been established.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-04T00:00:00ZQun CaiMeng-Jie SiXin-Ru ShiMeng LiaoFa-Chuang LiuMin WangKe-Xin LiYong-Ting ChenAn-Xin Wuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02001Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02001KMetal-Free Assembly of Diverse Polysubstituted Pyridines via an Efficient Cascade Approach of Tertiary Enaminones and α,β-Unsaturated Sulfonylketimines<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D3QO02001K, Research Article</div><div>Xiang Li, Qiwen Pang, Yang Zhang, Yang Li, Qian-Qian Yang, Xin-Yu Lin, Xin Xie, Wei Huang<br/>Herein, we report a metal-free, scalable, cascade protocol for constructing polysubstituted pyridines from N,N-dimethyl enaminones and α,β-unsaturated sulfonketimines by cleaving C–N/N–S bonds. This efficient methodology (up to 96% yield) assembles...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-10T00:00:00ZXiang LiQiwen PangYang ZhangYang LiQian-Qian YangXin-Yu LinXin XieWei Huanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00119Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00119BModular synthetic strategies for dipyrrolopyrazines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00119B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00119B, Research Article</div><div>Justin Kahle, Alexandra V. Mackenroth, Christopher Hüßler, Patrick D. Römgens, Paul Schimanski, Petra Krämer, Margit Brückner, Thomas Oeser, Frank Rominger, Matthias Rudolph, A. Stephen K. Hashmi<br/>Our work presents novel synthetic approaches for dipyrrolopyrazines. Modifying pyrrole and NH-moieties enhances versatility, facilitating their utilisation in materials science applications.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-04T00:00:00ZJustin KahleAlexandra V. MackenrothChristopher HüßlerPatrick D. RömgensPaul SchimanskiPetra KrämerMargit BrücknerThomas OeserFrank RomingerMatthias RudolphA. Stephen K. Hashmihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00023Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00023DNickel-free cross-electrophile coupling of unactivated alkyl bromides with thiosulfonates and sulfinyl sulfones<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00023D" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00023D, Research Article</div><div>Qiujin Fan, Yanchuang Zhao, Jintao Liang, Yan Zhang, Yuenian Xu, Qingqing Zhang, Hua Zhu, Min Jiang, Xinxin Shao<br/>An unusual zinc-promoted reductive coupling between alkyl bromides and thiosulfonates under nickel-free conditions is described.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-19T00:00:00ZQiujin FanYanchuang ZhaoJintao LiangYan ZhangYuenian XuQingqing ZhangHua ZhuMin JiangXinxin Shaohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00063Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00063CAdvancement in C–H Bond Alkylation of (Hetero)arenes Catalyzed by the Most Abundant Transition Metal - Iron<div><i><b>Org. Chem. Front.</b></i>, 2024, Accepted Manuscript<br/><b>DOI</b>: 10.1039/D4QO00063C, Review Article</div><div>Chandini Pradhan, Benudhar Punji<br/>Alkylation reaction stands as a crucial organic transformation, fostering privileged alkylated arenes and heteroarenes in molecular science. Over the past decade, utilization of the most abundant transition metal iron for...<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-07T00:00:00ZChandini PradhanBenudhar Punjihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02045Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02045BStraightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02045B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02045B, Research Article</div><div>Sien Liu, Yanjing Liao, Hongyi Li, Biping Xu, Xiaofeng Zhang, Yaping Shang, Weiping Su<br/>We report that the direct oxidative cross-coupling of carbonyl compounds with simple alkenes is realized to synthesize α-allylated carbonyl compounds by identifying the bisphosphine ligand BINAP that enables the copper catalyst to integrate two different catalytic cycles in a one-pot system.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-07T00:00:00ZSien LiuYanjing LiaoHongyi LiBiping XuXiaofeng ZhangYaping ShangWeiping Suhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00261Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00261JAdvanced 19F-NMR studies shed new light on encapsulation of isosteric guests in the hexameric capsules of resorcin[4]arenes and pyrogallol[4]arenes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00261J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00261J, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Sarit Slovak, Tamar Salem, Inbar Horin, Liat Avram, Yoram Cohen<br/><small> <sup>1</sup> </small>H/<small><sup>19</sup></small>F diffusion NMR and <small><sup>19</sup></small>F GEST NMR are utilized to characterize the encapsulation of bulky isosteric guests into the hexameric capsules of resorcin[4]arene and pyrogallol[4]arene.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-28T00:00:00ZSarit SlovakTamar SalemInbar HorinLiat AvramYoram Cohenhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00009Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00009ASynthesis of gem-difluorinated pentacyclic indenopyrazolopyrazolones via Rh(III)-catalyzed cascade C–H functionalization/[3 + 2] dipolar cycloaddition<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00009A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00009A, Research Article</div><div>Fu-Xiaomin Liu, Weijie Chen, Ying Cai, Zhi Zhou, Wei Yi, Kui Cheng<br/>A Rh(<small>III</small>)-catalysed cascade C–H functionalization/[3 + 2] dipolar cycloaddition was realized to deliver <em>gem</em>-difluorinated pentacyclic indenopyrazolopyrazolones with four continuous chiral carbon centres in a one-pot fashion.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZFu-Xiaomin LiuWeijie ChenYing CaiZhi ZhouWei YiKui Chenghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00082Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00082JPd((R)-DTBM-SEGphos)Cl2-catalyzed kinetic resolution of tertiary propargylic alcohols<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00082J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00082J, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Jie Wang, Wei-Feng Zheng, Yuling Li, Yin-Long Guo, Hui Qian, Shengming Ma<br/>A variety of optically active tertiary propargylic alcohols and tetrasubstituted 2,3-allenoic acids have been synthesized <em>via</em> a Pd((<em>R</em>)-DTBM-SEGphos)Cl<small><sub>2</sub></small>-catalyzed carboxylative kinetic resolution reaction of racemic tertiary propargylic alcohols.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-03-01T00:00:00ZJie WangWei-Feng ZhengYuling LiYin-Long GuoHui QianShengming Mahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00260Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00260ANickel catalyzed C–S cross coupling of sterically hindered substrates enabled by flexible bidentate phosphines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00260A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00260A, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Ivo H. Lindenmaier, Robert C. Richter, Ivana Fleischer<br/>The challenging nickel-catalyzed coupling of <em>ortho</em>-substituted aryl triflates with thiols was accomplished by employing a versatile bidentate ligand, capable of decoordination of one phosphorus atom during the deprotonation of thiol.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-29T00:00:00ZIvo H. LindenmaierRobert C. RichterIvana Fleischerhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00139Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00139GPhoto-induced catalyst-free formal carbon insertion of acylsilanes into B–B and B–Si bonds<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00139G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00139G, Research Article</div><div>Xiongxiong Lu, Qingbin Zhao, Hao Zhang, Pan Xu, Xuenian Chen, Zhenxing Liu<br/>A formal carbon insertion of acylsilanes into B–B and B–Si bonds has been developed. The <em>in situ</em> formed siloxycarbene under blue LED irradiation worked as the intermediate for the reaction. When 2-furyl and 2-thiophenyl acylsilanes were used, the B(pin) ring was enlarged to a six-membered ring.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-22T00:00:00ZXiongxiong LuQingbin ZhaoHao ZhangPan XuXuenian ChenZhenxing Liuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00106Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00106KCO2 and palladium enabled highly chemoselective hydroxylation of gem-difluorocyclopropanes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00106K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00106K, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Xingben Wang, Fang Xiao, Frederic W. Patureau<br/>A mild chemoselective CO<small><sub>2</sub></small> and palladium mediated hydroxylation method of <em>gem</em>-difluorocyclopropanes is herein reported, in the presence of water. A broad functional group tolerance and multiple mechanistic experiments are described and discussed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-21T00:00:00ZXingben WangFang XiaoFrederic W. Patureauhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01955Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01955AUnprecedented single-electron-transfer reduction-based N → C acyl migration reactions of imides enabled by redox-neutral photocatalysis<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01955A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO01955A, Research Article</div><div>Linge Huai, Li Zhang, Zhentao Wang, Yewen Fang<br/>N → C acyl migration: in the absence of a base, redox-neutral photocatalyzed acyl migration reactions have been realized <em>via</em> the reaction of <em>N</em>-vinylimides with alkyl radicals derived from alkyl silicates.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-19T00:00:00ZLinge HuaiLi ZhangZhentao WangYewen Fanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00064Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00064APalladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00064A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00064A, Research Article</div><div>Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng<br/>An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity <em>via</em> Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-28T00:00:00ZTing-Peng LiShuixiu SuJia-Huan ShenMeng ZangYang-Zi LiuQuannan WangWei-Ping Denghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00162Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00162APrins cyclization of 1,3-dioxinone: synthesis of 11-epi-badkhysin<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00162A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00162A, Research Article</div><div>Xiaoliang Xu, Ping Hua, Yiren Xu, Baoqing He, Jingfeng Zhao, Liang Li, Wen Chen, Hongbin Zhang<br/>The asymmetric synthesis of highly functional 11-<em>epi</em>-badkhysin has been accomplished using a structure-unit based approach.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-27T00:00:00ZXiaoliang XuPing HuaYiren XuBaoqing HeJingfeng ZhaoLiang LiWen ChenHongbin Zhanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01990Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01990JA dearomatization–rearomatization strategy for construction of 4H-quinolizin-4-ones via C–H bond functionalization of pyridines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01990J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO01990J, Research Article</div><div>Dong Qiu, Yijin Su<br/>Herein, the synthesis of 4<em>H</em>-quinolizin-4-ones from <em>N</em>-(2-methoxy-2-oxoethyl) pyridinium salts and alkenes through dearomative cycloaddition and rearomative ring expansion has been developed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZDong QiuYijin Suhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00217Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00217BFrustrated Lewis pair chemistry of alkynes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00217B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00217B, Review Article</div><div>Jing Guo, Maying Yan, Douglas W. Stephan<br/>This review is focused on the chemistry of frustrated Lewis pairs (FLPs) with alkynes and surveys the range of stoichiometric and catalytic reactions enabled by this concept.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZJing GuoMaying YanDouglas W. Stephanhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00167Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00167BNickel/photoredox-catalyzed carbonylative transformations of α-phosphorus-, α-sulfur-, and α-boron-substituted alkyl halides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00167B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00167B, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY.png' alt='Creative Commons Licence' border='none' /></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution 3.0 Unported Licence.</a></div><div>Le-Cheng Wang, Xiao-Feng Wu<br/>A novel dual nickel/photoredox catalyzed direct amino- and alkoxycarbonylation of α-heteroatom substituted organohalides has been developed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZLe-Cheng WangXiao-Feng Wuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00077Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00077CPhotoinduced alkylation of pyrazolones via β-scission of unstrained aliphatic alcohol derivatives<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00077C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00077C, Research Article</div><div>Xinxin Geng, Pan Tao, Yujun Li, Ke Zheng<br/>An efficient radical approach was reported for the transformation of unstrained aliphatic alcohols through the β-scission of alkoxyl radicals.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZXinxin GengPan TaoYujun LiKe Zhenghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00035Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00035HRegioselective electrochemical cascade C–H sulfonylation–bromination of indolizines to access difunctionalized indolizines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00035H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00035H, Research Article</div><div>Wenxuan Jiang, Xiang Liu, Chuanying Zhu, Meiyi Chen, Weidan Li, Hua Cao<br/>Regioselective electrochemical C–H sulfonylation–bromination between indolizines, sodium sulfinates, and KBr has been established in an undivided cell, in which KBr serves as both the brominating agent and electrolyte.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZWenxuan JiangXiang LiuChuanying ZhuMeiyi ChenWeidan LiHua Caohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00116Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00116HSelective photochemical synthesis of primary arylamines and symmetric diarylamines via amination of aryl bromides using Ni(NH3)6Cl2 as a nitrogen source and catalyst<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00116H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00116H, Research Article</div><div>Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue<br/>The selective synthesis of primary arylamines and diarylamines <em>via</em> coupling reactions with ammonia as a nitrogen source is still challenging.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-21T00:00:00ZZhehui XuJianyang DongGeyang SongFuqiang KongGang LiDong Xuehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00032Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00032CElectrochemical remote C(sp3)–H thiocyanation<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00032C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00032C, Research Article</div><div>Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li, Weisi Guo<br/>An electrochemical thiocyanation of distal C(sp<small><sup>3</sup></small>)–H bonds based on amidyl radical-mediated 1,5-HAT has been developed. The transformation is highly site-selective and compatible with primary, secondary, and tertiary sulfonamides, and bioactive derivatives.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-26T00:00:00ZXinyu PangHui HeXiangrui MengLinbao ZhangShaofei NiMing LiWeisi Guohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00073Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00073KOrigin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00073K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00073K, Research Article</div><div>Yujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv, Gang Lu<br/>Two major factors, <em>i.e.</em>, C–H σ orbital energy and C–H BDE, account for the HAT site-selectivity of carbohydrates with the quinuclidine radical cation.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-23T00:00:00ZYujie JiLingfei HuHan GaoYan-Bo WuXiangying LvGang Luhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02139Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02139DSynthesis, conformational properties, and molecular recognition abilities of novel prism[5]arenes with branched and bulky alkyl groups<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02139D" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02139D, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Rocco Del Regno, Paolo Della Sala, Ivan Vollono, Carmen Talotta, Placido Neri, Neal Hickey, Siddharth Joshi, Silvano Geremia, Carmine Gaeta<br/>The direct macrocyclization to prism[5]arenes of 2,6-dialkoxynaphthalenes with branched and bulky alkyl groups has been obtained in good yields. The chirality of these novel prism[5]arenes is stable on the NMR time scale.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-21T00:00:00ZRocco Del RegnoPaolo Della SalaIvan VollonoCarmen TalottaPlacido NeriNeal HickeySiddharth JoshiSilvano GeremiaCarmine Gaetahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00208Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00208CDeoxygenation of N-heterocyclic N-oxides using isopropanol as a recyclable reductant<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00208C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00208C, Research Article</div><div>Ho Kyeong Ryu, Yun Do Song, Jun Hee Lee<br/>An organic photoredox-based recyclable strategy that facilitates the chemoselective deoxygenation of various functionalised N-heterocyclic <em>N</em>-oxides is presented.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-20T00:00:00ZHo Kyeong RyuYun Do SongJun Hee Leehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01999Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01999CIron(III)/quinoxaline-derived N,N-ligand catalyzed oxygen transfer reaction of N-vinyl nitrones through selective 4π-electrocyclization and N–O bond cleavage<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01999C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO01999C, Research Article</div><div>Yan-Jiao Lu, Feng-Lan Lu, Jin-Qi Zhang, Chun-Hua Chen, Cui Liang, Xiao-Pan Ma, Dong-Liang Mo<br/>We describe an iron(<small>III</small>)/quinoxaline-derived N,N-ligand promoted <em>O</em>-transfer reaction of <em>N</em>-vinyl nitrones through selective <em>O</em>-4π-electrocyclization and N–O bond cleavage to prepare a variety of 2,5-dihydrooxazoles in good yields.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-20T00:00:00ZYan-Jiao LuFeng-Lan LuJin-Qi ZhangChun-Hua ChenCui LiangXiao-Pan MaDong-Liang Mohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00136Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00136BFe-catalyzed B–H and Si–H insertion reactions of gem-dihaloalkanes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00136B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00136B, Research Article</div><div>Xinyu Wang, Zhaobin Wang<br/>We present an approach involving Fe-catalyzed B–H and Si–H insertion of <em>gem</em>-dichloroalkanes. In contrast to previous strategies, our method uses <em>gem</em>-dihaloalkanes as non-stabilized carbene precursors and operates through a radical reaction pathway.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-23T00:00:00ZXinyu WangZhaobin Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00177Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00177JElectron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00177J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00177J, Research Article</div><div>Romain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas Poisson<br/>Herein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-23T00:00:00ZRomain LapierreLina TruongMatthieu HedouinHassan OulyadiBruno SchiaviAlexandre JeanPhilippe JubaultThomas Poissonhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02099Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02099AA general photoinduced oxidative strategy with molecular oxygen in water<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02099A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02099A, Research Article</div><div>Jianyu Gu, Hui Yang, Jinfei Deng, Dengbo Jiang, Kaizhuo Lv, Tao Wang, Qiuli Yao<br/>The photoinduced oxidation of a wide range of functional groups in water and O<small><sub>2</sub></small> is achieved by using diacetyl as a photosensitizer.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-21T00:00:00ZJianyu GuHui YangJinfei DengDengbo JiangKaizhuo LvTao WangQiuli Yaohttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02019Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02019CIridium-catalyzed reductive γ-lactonization of ortho-acylbenzoic acids in water: sustainable access to phthalides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02019C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02019C, Research Article</div><div>Yang Chen, Jingyu Zhang, Hongguang Du, Renshi Luo, Jiaxi Xu, Zhanhui Yang<br/>Iridium-catalyzed reductive γ-lactonization of <em>ortho</em>-acylbenzoic acids in water provides a practical and sustainable route to phthalides.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-21T00:00:00ZYang ChenJingyu ZhangHongguang DuRenshi LuoJiaxi XuZhanhui Yanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00215Fhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00215FA formal (3 + 2) annulation–Cannizzaro cascade of bifunctional peroxides for the synthesis of dihydrofurans<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00215F" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D4QO00215F, Research Article</div><div>Yiwei Chen, Min Gao, Qianlan Xu, Jiumeng Zhang, Lin Hu<br/>Tunable tandem processes of bifunctional peroxides allow the divergent construction of functionalized dihydrofurans and epoxides by simply changing the basic conditions.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-20T00:00:00ZYiwei ChenMin GaoQianlan XuJiumeng ZhangLin Huhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02025Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02025HCatalytic [4 + 1]-annulation of thioamides with carbenoid precursors<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02025H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02025H, Research Article</div><div>Vladimir G. Ilkin, Valeriy O. Filimonov, Irina A. Utepova, Tetyana V. Beryozkina, Pavel A. Slepukhin, Andrey A. Tumashov, Wim Dehaen, Vasiliy A. Bakulev<br/>Catalyst-controlled regioselective and diastereoselective reactions of thioamides with diazoamides and 1-sulfonyl-1,2,3-triazoles was developed. Enantioselective and gram-scale syntheses were performed.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-20T00:00:00ZVladimir G. IlkinValeriy O. FilimonovIrina A. UtepovaTetyana V. BeryozkinaPavel A. SlepukhinAndrey A. TumashovWim DehaenVasiliy A. Bakulevhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02029Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02029KStereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02029K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, Advance Article<br/><b>DOI</b>: 10.1039/D3QO02029K, Research Article</div><div>Rong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo Han<br/>An asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to &gt;99 : 1 er under mild conditions.<br/>To cite this article before page numbers are assigned, use the DOI form of citation above.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-02-20T00:00:00ZRong ZengXiang ZhangYuan-Yuan LeiZhuo-Zhuo ZhangMin JiangQing-Zhu LiJun-Long LiBo Hanhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01933Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01933KCu-catalyzed alkylarylation of alkenes via N-directed remote C(sp3)–H functionalization<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01933K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1484-1489<br/><b>DOI</b>: 10.1039/D3QO01933K, Research Article</div><div>Rong Rui, Bin Wang, Xiao-Jing Xu, Zhe Zhang, Xi Chen, Xue-Yuan Liu<br/>Herein, we report a copper-catalyzed alkylarylation reaction of alkenes using <em>N</em>-fluoroamides and arylboronic acids.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-29T00:00:00ZRong RuiBin WangXiao-Jing XuZhe ZhangXi ChenXue-Yuan Liuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02094Khttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02094KNi-catalyzed cross-coupling of heteroaryl sulfones and diselenides via deheteroaromatization and heteroaromatization: synthesis of heteroaryl selenides<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02094K" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1469-1472<br/><b>DOI</b>: 10.1039/D3QO02094K, Research Article</div><div>Xin-Yu Liu, Yu-Xin Dou, Muhammad Hasan, Weidong Rao, Daopeng Shen, Shusu Shen, Shun-Yi Wang<br/>A Ni-catalyzed cross-coupling reaction of heteroaryl sulfone compounds and diselenides to generate heteroaryl selenides is developed. This method features not only mild reaction conditions but also excellent functional group compatibility.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-24T00:00:00ZXin-Yu LiuYu-Xin DouMuhammad HasanWeidong RaoDaopeng ShenShusu ShenShun-Yi Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00033Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00033ACycloparaphenylene-based [2]catenanes: interlocking the carbon nanohoops<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00033A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1490-1494<br/><b>DOI</b>: 10.1039/D4QO00033A, Highlight</div><div>Wei-Tao Xu, Wei Wang<br/>In this highlight, recent advances in the design and synthesis of novel cycloparaphenylene (CPP)-based [2]catenanes are presented, with an emphasis on the design strategy and further investigations on their attractive properties.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-24T00:00:00ZWei-Tao XuWei Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01939Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01939JAsymmetric palladium-catalyzed decarboxylative [3 + 2] cycloaddition: straightforward construction of chiral spiro-heterocyclic scaffolds<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01939J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1479-1483<br/><b>DOI</b>: 10.1039/D3QO01939J, Research Article</div><div>Ke Zhang, Pengyuan You, Sheng Zuo, Yuan Tao, Fen-er Chen<br/>We developed an asymmetric Pd-catalyzed [3 + 2] cycloaddition of α,β-unsaturated pyrazolones with vinylethylene carbonates. An array of spiro-tetrahydrofuran-pyrazolones were obtained in high yields with excellent enantioselectivities.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-20T00:00:00ZKe ZhangPengyuan YouSheng ZuoYuan TaoFen-er Chenhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01980Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01980BSite-selective editing of peptides via backbone modification<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01980B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1623-1640<br/><b>DOI</b>: 10.1039/D3QO01980B, Review Article</div><div>Junjie Shi, Tong Sun, Mingyu Yang<br/>The site-selective modifications of peptide backbones have a significant impact on peptide conformation, folding ability, and physicochemical and biological properties. This review discusses the site-selective modifications of peptide backbones and classifies them into four categories.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-19T00:00:00ZJunjie ShiTong SunMingyu Yanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00058Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D4QO00058GA green and facile photochemical thiolate-catalyzed strategy for borylation of aryl fluorides with NHC–borane<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D4QO00058G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1462-1468<br/><b>DOI</b>: 10.1039/D4QO00058G, Research Article</div><div>Yu-Qi Miao, Qiao-Jing Pan, Jia-Xin Kang, Xusheng Dai, Zhenxing Liu, Xuenian Chen<br/>Mild conditions, no photocatalyst, broad substrate scope.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-19T00:00:00ZYu-Qi MiaoQiao-Jing PanJia-Xin KangXusheng DaiZhenxing LiuXuenian Chenhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02013Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02013DSynthesis of branched-chain sugars and higher-carbon sugars enabled by site-selective C–H alkylation relying on 1,5-hydrogen atom transfer of ethylenoxy radicals<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02013D" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1332-1340<br/><b>DOI</b>: 10.1039/D3QO02013D, Research Article</div><div>Dongwei Li, Lingjun Wang, Jianjun Wang, Peng Wang, Ni Song, Pengwei Chen, Ming Li<br/>Branched-chain sugars and higher-carbon sugars have been efficiently prepared by site-selective C–H alkylation mediated by 1,5-HAT of ethylenoxy radicals.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-18T00:00:00ZDongwei LiLingjun WangJianjun WangPeng WangNi SongPengwei ChenMing Lihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02034Ghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02034GEnantioselective total syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine enabled by Ir-catalysed asymmetric hydrogenation of all-carbon tetrasubstituted cycloalkenes<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02034G" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1456-1461<br/><b>DOI</b>: 10.1039/D3QO02034G, Research Article</div><div>Kai Zhang, Peng Cui, Miao Miao, Meiqi Zeng, Xu Wang, Minjie Zhang, Qifeng Chen, Hao Song, Bowen Ke, Yong Qin<br/>Syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine are reported based on Ir-catalysed asymmetric hydrogenation of tetrasubstituted α-acylpyrazole-β-alkyl cycloalkenes to construct piperidine rings bearing 1,2-contiguous <em>cis</em>-stereocenters in high yields and excellent enantioselectivities.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-17T00:00:00ZKai ZhangPeng CuiMiao MiaoMeiqi ZengXu WangMinjie ZhangQifeng ChenHao SongBowen KeYong Qinhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01943Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01943HPalladium catalyzed remote-meta-C–H functionalization of aniline scaffolds<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01943H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1473-1478<br/><b>DOI</b>: 10.1039/D3QO01943H, Research Article</div><div>Dasari Srinivas, Gedu Satyanarayana<br/>Here, we report on a microwave-assisted accelerated <em>meta</em>-C–H olefination of aniline derivatives using a simple aliphatic end-on nitrile assembly. Notably, the protocol shows broad substrate compatibility with remarkable regio-selectivity.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-16T00:00:00ZDasari SrinivasGedu Satyanarayanahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02062Bhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02062BDirect access to hydrazides and amides from carboxylic acids via acyloxyphosphonium ion<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02062B" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1450-1455<br/><b>DOI</b>: 10.1039/D3QO02062B, Research Article</div><div>Aparna Tyagi, Chinmoy K. Hazra<br/>Adding an amine moiety to a carbonyl group poses a challenging synthetic task; nevertheless, it is a crucial step in developing numerous bioactive molecules.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-16T00:00:00ZAparna TyagiChinmoy K. Hazrahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01940Chttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01940CPalladium-catalyzed thiocarbonylation of alkenes toward branched thioesters using CO2<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01940C" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1322-1331<br/><b>DOI</b>: 10.1039/D3QO01940C, Research Article</div><div><img alt='Open Access' src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/open_access_blue.png' /> Open Access</div><div><a rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window'> <img src='http://sod-a.rsc-cdn.org/pubs.rsc-uat.org/content/NewImages/CCBY-NC.png' alt='Creative Commons Licence' border='none'/></a>&nbsp This article is licensed under a <a text-decoration=none rel='license' href='http://creativecommons.org/licenses/by-nc/3.0/' target='_blank' title='This link will open in a new browser window' >Creative Commons Attribution-NonCommercial 3.0 Unported Licence.</a></div><div>Huan Wang, Chen Li, Yudong Li, Jianbin Chen, Shaoli Liu, Yuehui Li<br/>Thiocarbonylation of alkenes using CO<small><sub>2</sub></small> was developed for the preparation of a broad array of thioesters. By the combination of Pd catalyst and N–P type carbazophosphine ligand, the reactivity and selectivity were well tuned.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-16T00:00:00ZHuan WangChen LiYudong LiJianbin ChenShaoli LiuYuehui Lihttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01606Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01606DVisible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones to construct functionalized aryltetrafluoroethane derivatives<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01606D" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1444-1449<br/><b>DOI</b>: 10.1039/D3QO01606D, Research Article</div><div>Miaomiao Mu, Xiaolei Zhu, Jinshan Li, Manman Sun, Jianguo Yang, Guobo Huang, Lei Wang, Zhiming Wang<br/>A visible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones has been developed.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-15T00:00:00ZMiaomiao MuXiaolei ZhuJinshan LiManman SunJianguo YangGuobo HuangLei WangZhiming Wanghttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01909Hhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01909HChiral phosphoric acid-catalyzed enantioselective synthesis of functionalized pyrrolinones containing a geminal diamine core via an aza-Friedel–Crafts reaction of newly developed pyrrolinone ketimines<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01909H" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1437-1443<br/><b>DOI</b>: 10.1039/D3QO01909H, Research Article</div><div>Tong Zhang, Zhen-Hua Wang, Yong Li, Jian-Qiang Zhao, Yong You, Yan-Ping Zhang, Jun-Qing Yin, Wei-Cheng Yuan<br/>A class of novel pyrrolinone ketimines was synthesized for the first time and applied to the asymmetric aza-Friedel–Crafts reaction with phenolic compounds.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-15T00:00:00ZTong ZhangZhen-Hua WangYong LiJian-Qiang ZhaoYong YouYan-Ping ZhangJun-Qing YinWei-Cheng Yuanhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01748Fhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01748FDesign of rigid chiral bipyridine-2NO tetradentate ligands: application in asymmetric catalysis<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01748F" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1314-1321<br/><b>DOI</b>: 10.1039/D3QO01748F, Research Article</div><div>Yu-Heng Wang, Pan Hu, Xi-Rui Wang, Ke-Lan Xu, Qi-Lin Wang, Hui-Juan Wang, Xiong-Li Liu<br/>A new class of chiral bipyridine-2NO ligands, which incorporate the advantages of both the bipyridine skeleton and the pyrroloimidazolone-based <em>N</em>-oxide moiety, was developed.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-15T00:00:00ZYu-Heng WangPan HuXi-Rui WangKe-Lan XuQi-Lin WangHui-Juan WangXiong-Li Liuhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01908Jhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01908JPhoto-induced 1,2-alkylarylation/cyclization of alkenes, alkyl halides and N-alkylindoles via an EDA-complex<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01908J" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1412-1419<br/><b>DOI</b>: 10.1039/D3QO01908J, Research Article</div><div>Tao Ju, Min Ge, Li-Hang Ren, Ai-Ling Lu, Zhi-Hao Wang, Shi-Ji He, Jing Sun, Ying Han, Chao-Guo Yan<br/>Herein, we developed a photo-induced 1,2-alkylarylation and 1,2-alkylarylation cyclization of alkenes, alkyl halides and <em>N</em>-alkylindoles to synthesize indoles derivatives and polysubstituted tetrahydrofuran under mild conditions without the use of external redox reagents and photosensitizers.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-13T00:00:00ZTao JuMin GeLi-Hang RenAi-Ling LuZhi-Hao WangShi-Ji HeJing SunYing HanChao-Guo Yanhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01900Dhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01900DStereoselective hydrodefluorination of CF3-substituted alkenes and gem-difluoroalkenes by H−<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01900D" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1388-1394<br/><b>DOI</b>: 10.1039/D3QO01900D, Research Article</div><div>Dachang Bai, Xin Li, Fen Wu, Junbiao Chang<br/>Zn-catalyzed stereoselective hydrodefluorination of CF<small><sub>3</sub></small>-substituted alkenes, <em>gem</em>-difluoroalkenes and polyfluoroarenes by hydride ion addition has been realized through controlled C(sp<small><sup>3</sup></small>)–F and/or C(sp<small><sup>2</sup></small>)–F bonds cleavage.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-12T00:00:00ZDachang BaiXin LiFen WuJunbiao Changhttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01855Ehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO01855EAccess to α-all-carbon quaternary amides through the hydroamidation of allenes using DIBAL-H and isocyanates<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO01855E" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1366-1371<br/><b>DOI</b>: 10.1039/D3QO01855E, Research Article</div><div>Kyeongmin Lee, Soohong Cho, Seeun Lim, Yunmi Lee<br/>A regio- and stereoselective hydroamidation of allenes using diisobutylaluminum hydride and isocyanates is described, resulting in the formation of α-quaternary amides.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-12T00:00:00ZKyeongmin LeeSoohong ChoSeeun LimYunmi Leehttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02085Ahttp://pubs.rsc.org/en/Content/ArticleLanding/2024/QO/D3QO02085AEnantioselective construction of chiral gem-difluorinated C2-quaternary indoline via dual MgSO4–CPA-catalyzed asymmetric Mannich reactions<div><p><img align="center" src="/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=D3QO02085A" /></p></div><div><i><b>Org. Chem. Front.</b></i>, 2024, <b>11</b>,1430-1436<br/><b>DOI</b>: 10.1039/D3QO02085A, Research Article</div><div>Xin-Chun Wang, Xing-Pin Wei, Chang-Peng Zou, Tao Ma, Yonghui He, Ganpeng Li, Xiao-Jing Zhao<br/>Herein, the synthesis of 2-(3,3-difluoro-2-phenylindolin-2-yl)-1-phenylethan-1-one scaffolds through asymmetric Mannich reactions between 3,3-difluoro cyclic ketimines and simple ketones is described.<br/>The content of this RSS Feed (c) The Royal Society of Chemistry</div>2024-01-10T00:00:00ZXin-Chun WangXing-Pin WeiChang-Peng ZouTao MaYonghui HeGanpeng LiXiao-Jing Zhao