RSC - React. Chem. Eng. latest articles

Synergistic H2 activation and structural stabilization by Ag doping in CoO catalysts for enhanced dicyclopentadiene hydroformylation

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00093B, Paper

Yuxia Li, Tingting Ge, Zehao Jing, Yanxia Zheng, Yuchao Li, Ming Wang, Haofei Huang, Cuncun Zuo
The Ag/CoO catalyst promotes H₂ activation and increases active sites, enabling efficient and stable hydroformylation reactions.
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Polystyrene-supported aminobenzenesulfonic acids as bifunctional heterogeneous catalysts for the synthesis of isoxazoline skeletons

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00067C, Communication

Open Access

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Kai Takizawa, Takuma Ishihara, Shinki Tani, Yusuke Hamada, Tadafumi Uchimaru, Akira Yada, Shun-ya Onozawa, Kazuhiko Sato, Shū Kobayashi
The isoxazoline skeleton is a pivotal structural motif in pharmaceuticals and agrochemicals, necessitating the development of efficient synthetic methodologies.
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A Robust Co/SiO₂ Catalyst for Sustainable Sorbitol Production: From Batch to Continuous Flow

React. Chem. Eng., 2026, Accepted Manuscript
DOI: 10.1039/D6RE00099A, Paper

Xincheng Wang, Bangxian Long, Yuze Peng, Yuxin Liang, Haofei Yang, Lei Wang, Miaomiao Chen, Ruomeng Li, Songqi Tai
The development of efficient non-noble metal catalysts for glucose hydrogenation to sorbitol is essential for sustainable biomass valorization. Herein, a robust Co/SiO₂ catalyst prepared by incipient wetness impregnation is reported....
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Correction: Photocatalytic butanol reforming for hydrogen production using Ag2O/TiO2 composite catalysts: effects of Ag2O loading, calcination temperature, and reaction parameters

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE90013E, Correction

Open Access

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Tumelo Seadira, Thabelo Nelushi, Gullapelli Sadanandam, Dieketseng Tsotetsi, Ismaila T. Bello, Mokhotjwa S. Dhlamini
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Advanced capillary sampling technique for spatially resolved analysis of complex gas mixtures

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D5RE00531K, Paper

Open Access

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Lisa Nordhausen, Marie Denise Gutsch, Daniel Hodonj, Marion Börnhorst
A coil-based sampling extension was implemented to enable the integration of a capillary-based sampling method with FTIR analysis.
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Photocatalytic butanol reforming for hydrogen production using Ag2O/TiO2 composite catalysts: effects of Ag2O loading, calcination temperature, and reaction parameters

React. Chem. Eng., 2026, 11,1015-1025
DOI: 10.1039/D5RE00384A, Paper

Open Access

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Tumelo Seadira, Thabelo Nelushi, Gullapelli Sadanandam, Dieketseng Tsotesi, Ismaila T. Bello, Mokhotjwa S. Dhlamini
Over recent years, photocatalytic biomass reforming for hydrogen production has gained research attention as an alternative to the inefficient water-splitting reaction, which requires a standard Gibbs free energy of 237 kJ mol⁻¹.
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Thermal conversion behavior of pyrazole-3,5-dicarboxylate-substituted octacalcium phosphate

React. Chem. Eng., 2026, 11,1008-1014
DOI: 10.1039/D6RE00031B, Communication

Shimon Konosu, Kazuto Sugimoto, Iori Yamada, Motohiro Tagaya
We investigated the thermal behavior of pyrazole-3,5-dicarboxylic acid (PD)-substituted octacalcium phosphate. The PD-modulated hydrogen-bonding network suggested effectively localized conversion toward an apatite-like structure upon the heat.
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The Saccharomyces cerevisiae factory-driven efficient glucaric acid production: from metabolic engineering to process optimization

React. Chem. Eng., 2026, 11,991-1007
DOI: 10.1039/D6RE00053C, Review Article

Zijuan Wu, Alan Yan, Tianpeng Chen, Wenjun Sun, Chenglun Tang, Yong Chen
Glucaric acid, a high-value platform compound derived from renewable resources, has garnered increasing attention due to its broad applications in food additives, pharmaceutical precursors, and green chemical industries.
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Adsorption-assisted photocatalytic removal of melanoidin from water by a nitrogen-rich covalent organic framework

React. Chem. Eng., 2026, 11,1148-1156
DOI: 10.1039/D6RE00013D, Paper

Xuhui Zhang, Wenju Zhang, Hui Guo, Junyou Shi, Dan Zhang
Melanoidin (MD), a refractory macromolecule pollutant common in industrial wastewater, presents significant environmental challenges due to its chemical stability and resistance to biodegradation.
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Numerical investigation of aluminium hydrochlorination in a fluidized bed reactor via the MP-PIC model

React. Chem. Eng., 2026, 11,1127-1137
DOI: 10.1039/D5RE00523J, Paper

Vinay Yadav, Farrukh Khalid
This work reports the preliminary investigation of the aluminium hydrochlorination reaction through simulation using the MP-PIC approach.
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High-throughput experimentation for the application in oxidation reactions: solid dispensing approach for miniaturised reactions

React. Chem. Eng., 2026, 11,1117-1126
DOI: 10.1039/D5RE00471C, Paper

Open Access

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Fulufhelo Radzilani, Orpah Zinyemba, Reinout Meijboom
A SiO₂-based solid-dispensing method enables HTS of Cu-catalysed oxidative esterification of benzaldehyde to identify optimal reaction conditions across 96 parallel reactions.
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Innovative ZSM-5-based catalyst design via 3D printing for methanol dehydration to DME

React. Chem. Eng., 2026, 11,1059-1073
DOI: 10.1039/D6RE00015K, Paper

Open Access

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V. Koidi, S. Koltsakidis, S. Karakoulia, D. Tzetzis, A. A. Lappas, E. Heracleous
3D printing was successfully employed to fabricate structured ZSM-5-based catalysts with high catalytic activity in the methanol-to-DME reaction, good resistance to coke formation and high mechanical strength.
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Alkaline silver nitrate exhibits versatility in the instant oxidation of furans to bioplastic precursors and its mechanistic insights

React. Chem. Eng., 2026, 11,1157-1174
DOI: 10.1039/D5RE00509D, Paper

Ravi Kumar Kunchala, Meera Cheviri, Paramdeep Kaur, Bhawana Devi, Lakshmanan Potturaja, Vishnu Bakthavachalam, Senthil Murugan Arumugam, Alisha Alisha, Jyoti Baghel, Sasikumar Elumalai
The AgNO₃–KOH system offering Ag⁺ and Ag₂O active species enables rapid conversion of furfural to 2-furoic acid and of 2,5-diformylfuran to 2,5-furandicarboxylic acid. The silver nanoparticles, a by-product, show potential in wastewater treatment.
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Zeolite-catalyzed solvent-free transoximation of carbonyl compounds and cyclohexanone oxime

React. Chem. Eng., 2026, 11,1138-1147
DOI: 10.1039/D5RE00514K, Paper

Mengting Li, Yongrui Wang, Yibin Luo, Xingtian Shu
Cyclohexanone oxime (CHO) and cyclododecanone (CDON) were transformed to cyclododecanone oxime (CDOX) and cyclohexanone (CYC) by transoximation reaction with HY zeolite under solvent-free condition through the reaction–distillation coupling process.
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Preparation of metal-based ionic liquid catalysts and their application to degrade waste polyester fiber

React. Chem. Eng., 2026, 11,1094-1107
DOI: 10.1039/D5RE00388A, Paper

Ruitong Ma, Bing Liu, Ruibo Wang, Zhijiong Wu, Liying Guo
The invention relates to a preparation of metal-based ionic liquid catalysts and their application to degrade waste polyester fiber.
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Development and evaluation of operational parameter driven mechanistic and empirical kinetic models for photocatalytic degradation of emerging contaminants

React. Chem. Eng., 2026, 11,1074-1093
DOI: 10.1039/D5RE00491H, Paper

Pubali Mandal, Abhradeep Majumder, Lavanya Bonthu, Alagu Lavanya Thangaperumal, Manoj Kumar Yadav, Ahalya S, Nadeem A. Khan
Development and identification of the best-suited operational parameter-driven (pH, photocatalyst dose, contaminant concentration, and light intensity) model for describing the degradation kinetics during photocatalysis.
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Mechanistic insights into the thermal pyrolysis of high-density polyethylene and polypropylene: towards sustainable hydrogen production and carbon valorization

React. Chem. Eng., 2026, 11,1026-1039
DOI: 10.1039/D5RE00442J, Paper

Open Access

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Vanessa Maria Pohl, Cedric Karel Fonzeu Monguen, Dominik Julian Heitlinger, Patrick Lott, Olaf Deutschmann
This study systematically investigates how plastic type and reactor temperature determine the gaseous, liquid, and solid products generated during high-temperature pyrolysis of plastic waste for hydrogen and carbon production.
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Nanostructured CeO2 with different morphologies for methoxycarbonylation of 2,4-toluene diamine with dimethyl carbonate

React. Chem. Eng., 2026, 11,1040-1052
DOI: 10.1039/D5RE00469A, Paper

Mengli Dong, Han Yu, Xinqiang Zhao, Yao Lu, Hualiang An, Yanji Wang
The acid sites and lattice oxygen on CeO₂ synergistically catalyze the synthesis of TDC from TDA and DMC. The by-product N-methylated TDA can be suppressed by decreasing oxygen vacancies of CeO₂.
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Valuable carbon nanomaterials directly prepared from CO2via sonication in pure water

React. Chem. Eng., 2026, 11,1053-1058
DOI: 10.1039/D5RE00421G, Paper

Jungwen Yeh, Yuki Moriya, Masaya Uchida
Room-temperature sonication in water converts CaCO₃/Ca(OH)₂ into CNO-enriched carbons with 20–30 nm concentric shells via atmospheric CO₂ capture.
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Model based process optimization for nanoparticle precipitation

React. Chem. Eng., 2026, 11,1108-1116
DOI: 10.1039/D5RE00333D, Paper

Open Access

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Andrea Gilch, Adeel Muneer, Jana Dienstbier, Lukas Pflug
This study presents a derivative-based optimization framework for nanoparticle synthesis. PBEs coupled with the exact Method of Moments enable optimal dynamic reactant inflow to minimize size variance while achieving a target mean diameter.
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Low-H2O2-consumption Mg-doped BC/ZnO/g-C3N4 catalysts for efficient pollutant degradation via enhanced electron transfer

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00105J, Paper

Yanping Zheng, Fang Liu, Liye He, Na Wen, Honghong Rao, Yuli Wei
A novel Mg-doped catalyst was synthesized via a one-pot thermal reduction method. Mg functions as an electron mediator to boost charge transfer and reaction efficiency.
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Interfacial engineering of rhodium-complex-integrated COF photocatalysts for photo-redox co-factor cycling and selective CO2 reduction

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D5RE00566C, Communication

Shaifali Mishra, Rajesh K. Yadav, Chandani Singh, Rehana Shahin, Kanchan Sharma, Jin OoK Baeg, Kamlesh Kumar, Mohit, Joonghan Kim
Solar-driven CO₂ conversion into valuable chemicals is a promising strategy for sustainable energy and carbon management.
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Construction of an Ni3V2O8/CoMoO4 core–shell heterostructure with urea as an additive and its capacitive properties in high-performance asymmetric supercapacitors

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00051G, Paper

Wei Xu, An li, Jian Hao, Tingting Hao, Yabin Wang, Zheng Zhao, Fengyu Wang, Jing Wang
In this work, a core–shell Ni₃V₂O₈@CoMoO₄-A cathode with a Ni₃V₂O₈ nanowire core and vertically coated CoMoO₄ nanosheet shell is synthesized via a two-step hydrothermal method using urea as a morphology regulator.
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Dual-OSDA ultrafast synthesis of AFX zeolite for enhanced catalytic performance in selective catalytic reduction of NOx with NH3

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00038J, Paper

Open Access

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Y. Qin, M. Takemoto, H. Fujinuma, S. P. Elangovan, Y. Yanaba, T. Okubo, T. Wakihara
This paper presents a dual-OSDA approach for the ultrafast synthesis of AFX zeolite, addressing challenges in terms of cost and synthesis efficiency.
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Tuning Mg-Al Hydrotalcite Structure through Mg/Al Ratio and K2CO3 Impregnation for Enhanced Biodiesel Catalysis

React. Chem. Eng., 2026, Accepted Manuscript
DOI: 10.1039/D6RE00080K, Paper

Jingdi Zheng, Yage Li, Tengfei Liu, Ying Tang, Kefan Wang, Yafei Liu
A series of hydrotalcites were synthesized via co-precipitation, modified by incipient wetness impregnation and calcined to form layered double oxides (LDOs). Comprehensive characterizations revealed that the catalyst with a Mg/Al...
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Synergistic catalysis and deactivation analysis of Ru/ZnO/C in hydrogen-transfer reductive catalytic fractionation of poplar wood

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00054A, Paper

Wenjing Guo, Qing Zhao, Yadong Bi, Kailin Wang, Mengming Wang, Baozhen Wu, Xinli Tong
During hydrogen-transfer RCF of poplar wood, 1 wt% Ru/ZnO/C achieved 34.2% total phenolic monomer yield, outperforming commercial 5 wt% Ru/C despite lower Ru loading, attributed to synergy between ZnO-derived Lewis acid sites and Ru nanoparticles.
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Selective synthesis of secondary imines via reductive coupling of aldehydes with ammonia over encapsulated NiFe alloy catalysts

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00063K, Paper

Yulong Lei, Jianguo Liu
One-pot imine synthesis from biomass aldehydes and ammonia. High selectivity (>98%) via the NiFe@CS core–shell catalyst. Ammonia competitive adsorption boosts selectivity in reductive amination.
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Automated analysis of DFT output files for molecular descriptor extraction and reactivity modeling

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00049E, Paper

Open Access

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Yu-Chien Huang, Dennis Chung-Yang Huang, Yun-Cheng Tsai
Accelerating structure–property and reactivity discovery by bridging computational quantum descriptors with experimental data in an automated workflow.
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WO3-modified KIT-6 catalysts synthesized via a non-hydrolytic sol–gel method for glycerol dehydration to acrolein

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00079G, Paper

Open Access

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Busra Kaya, Mohammed Alfatih Hamid, Yasar Zengin, Mehtap Safak Boroglu, Ismail Boz
Acrolein formation from glycerol over WO₃/KIT-6 is governed by the balance between medium-strength acidity and the Brønsted/Lewis acid site distribution, with optimal performance at 25 wt% WO₃.
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Enhanced dark catalysis reduction of organic dyes and heavy-metal pollutants over activated carbon-supported V/S-BiOBr

React. Chem. Eng., 2026, Accepted Manuscript
DOI: 10.1039/D6RE00037A, Paper

Mengistu Tadesse Mosisa, Samuel Ndaghiya Adawara, Adugna Boke Abdeta, Benjamin Kunkadma Inusa, Cuizhu Li, Haoyu Wang, Kening Xiang, Dong-Hau Kuo, Jinguo Lin, Xiaoyun Chen
This paper explores how the strategic immobilization of vanadium and sulfur co-doped bismuth oxybromide (V/S-BiOBr) nanoparticles on to activated carbon (AC) scaffolds can be used to address the problem of...
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Structures of complexes formed by organophosphorus acid extractants and divalent metal ions

React. Chem. Eng., 2026, Accepted Manuscript
DOI: 10.1039/D6RE00061D, Paper

Open Access

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Stijn Raiguel, Femke Derison, Koen Binnemans
The structure of the metal-extractant complexes was investigated for Mg(II), Ca(II), Mn(II), Ni(II), Cu(II) and Zn(II) after solvent extraction by bis(2-ethylhexyl)phosphoric acid (D2EHPA) and bis(2,4,4-trimethylpentylphosphinic acid) (Ionquest® 290). A combination...
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Clean technology of manganese extraction from low grade refractory manganese ore by suspension calcination based on mineral phase transformation

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00073H, Paper

Xuyang Yu, Wentao Zhou, Yanqing Qin, Jiali Chen
Conventional methods for roasting manganese ore frequently exhibit complex characteristics that lead to suboptimal resource utilization, failing to satisfy industrial standards for efficient manganese enrichment.
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Hydrazone-Linked DNP-Functionalized PLA Photocatalyst for Sustainable HAT-Mediated Hydroalkylation and NADH-Assisted Enzymatic CO₂-to- C₁ Fuel Conversion

React. Chem. Eng., 2026, Accepted Manuscript
DOI: 10.1039/D5RE00564G, Paper

Kanchan Sharma, Rajesh K. Yadav, Rajesh Kumar Verma, Chandani Singh, Shaifali Mishra, Rehana Shahin, Jin-Ook Baeg
This work presents a novel hybrid photocatalyst synthesized by integrating 2,4-dinitrophenylhydrazine (DNP) with poly(lactic acid) (PLA), yielding a hydrazone-linked DNPHz-PLA that combines photochemical reactivity with biocompatibility. Comprehensive characterization (AFM, TEM,...
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Continuous microreactor synthesis of size-controlled Ru nanoparticles to probe support and size effects in ammonia cracking

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00024J, Paper

Open Access

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Joseph El-Kadi, Laura Torrente-Murciano
This work reveals size–activity relationships in structurally sensitive reactions such as ammonia cracking by decoupling support and size effects through post-synthesis support of size-controlled flow synthesis nanoparticles.
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Dynamic estimation of the overall heat transfer coefficient in temperature oscillation calorimetry based on co-frequency response identification

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00064A, Paper

Dong Li, Shuliang Ye, Tianlong Xu
A co-frequency response identification method with physical regularization enables robust dynamic UA estimation in temperature oscillation calorimetry and improves Q_r calculation under severe exothermic conditions.
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Water and methanol cofeeding modulates kinetics in crude-to-chemical cracking

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D5RE00525F, Paper

Open Access

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Isa Al Aslani, Juan Manuel Colom, Gontzal Lezcano, Arwa Alahmadi, Tuiana Shoinkhorova, Alla Dikhtiarenko, Mengmeng Cui, Lujain Alfilfil, Sultan Alsalman, Isidoro Morales Osorio, Khalid Almajnouni, Pedro Castaño, Jorge Gascon
Co-processing crude oil with green methanol can integrate renewable carbon into refining, but water and other hydrophilic compounds like methanol can strongly affect catalyst behavior, product selectivity, and overall process efficiency.
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Lithium diisopropylamide-mediated aldol condensation of ethyl acetate and 3-pyridine aldehyde: batch limitations and advantages of continuous processing

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00068A, Paper

Letao Guo, Mei Yang, Lixia Yang, Mei Han, Wenna Tang, Guangwen Chen
Lithium diisopropylamide (LDA)-mediated aldol condensation is a fundamental method for the synthesis of β-hydroxy esters.
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Data-augmented response surface methodology-machine learning hybrid model for predicting polyvinyl butyral synthesis

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00081A, Paper

Yingying Liu, Chi Ying Vanessa Li, Liang Gao
LHS augmented RSM–SVR with hyperparameter tuning yields stable test predictions and strong validation set extrapolation; SHAP reveals n-butanal and HNO₃ synergy, and this framework links design, data augmentation, tuning, and interpretability for small sample multiphase synthesis.
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Kinetic insights into soybean peroxidase-catalyzed degradation of persistent organic pollutants

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D5RE00547G, Paper

Open Access

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Alexandre Santuchi da Cunha, Monica Rigoletto, Ardson dos Santos Vianna Jr., Enzo Laurenti
Enzymatic degradation of organic pollutants by means of peroxidase extracted from soybean hulls. A multi-substrate kinetic model allows to understand the interactions between different molecules and simulate the reaction mechanism well.
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Studying deactivation pathways of molecular catalysts ex situ: an accessible method using standard analytical equipment

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00082G, Paper

Open Access

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Lisa Steinwachs, Sven Störtte, Peter McNeice, Andreas J. Vorholt
The catalyst stability was monitored using a new ex situ approach based on standard analytical techniques, enabling the identification of ligand degradation pathways and providing a basis for real-time optimization of reaction conditions.
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Structural engineering of Pd/C catalyst for selective hydrogenation of bulky quinone to biphenol

React. Chem. Eng., 2026, Advance Article
DOI: 10.1039/D6RE00036C, Paper

Yuze Peng, Ziqiang Han, Haofei Yang, Yuxin Liang, Bangxian Long, Miaomiao Chen, Ruomeng Li, Songqi Tai, Xincheng Wang, Long Huang
Structural engineering of Pd/C with highly dispersed Pd nanoparticles (∼4.1 nm) enables selective hydrogenation of bulky TBDPQ to TBBP under mild conditions (100 °C, 3 MPa H₂), achieving 98.5% conversion and 99.0% selectivity.
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