RSC - Chem. Sci. latest articles

Stereoselective, Borane-catalysed Synthesis of syn-β-Hydroxyketones from α,β-Unsaturated Ketones

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC03052A, Edge Article

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Julie Macleod, Alastair Nimmo, Joseph Cockcroft, Paula Dominguez-Molano, Gary Stephen Nichol, Stephen P. Thomas
The reductive aldol reaction is a powerful tool for the regiocontrolled coupling of α,β-unsaturated compounds with aldehydes. The use of stoichiometric organoborane reductants has previously been reported. Here these reagents...
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Scaling up mechanochemical reactions: linking crystalline phase evolution studied via in situ PXRD with kinetics from MCR-ALS

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01158F, Edge Article

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Laura Macchietti, Maria Carta, Francesco Delogu, Fabrizia Grepioni, Franziska Emmerling, Lucia Casali
The proposed in situ PXRD/MCR-ALS platform resolves complex phase evolution and derives kinetic models to advance mechanochemical scale up.
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Design of a site selective heterochromic bimetallic lanthanide coiled coil with nanometre-scale control

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00813E, Edge Article

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Louise Slope, Anokhi Shah, Michael Taylor, Valentina Borghesani, Simon Caulton, Nikolas Brooks, Kate Hadley, Georgina Rose, Robert Hunter, Hassane El Mkami, Graham Smith, Aneika Corrine Leney, Niklaas Jan Buurma, Andrew Lovering, Janet E Lovett, Anna Peacock
Lanthanide-protein scaffolds hold significant promise for the design of functional biomaterials. Yet the selective incorporation of multiple lanthanide ions with distinct properties into discrete sites at tuneable distances within a...
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Golden Immunity: Gold Complexes as Emerging Triggers of Immunogenic Cell Death

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC02555B, Perspective

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Marta Redrado, M. Concepción Gimeno
Cancer immunotherapy has transformed modern oncology, yet its clinical success remains limited by the intrinsically low immunogenicity of many solid tumours. Immunogenic cell death (ICD) has emerged as a powerful...
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Reversible Ionic Aggregation Kinetics in Concentrated Electrolytes

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01986B, Edge Article

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Zachary Anthony Holmes Goodwin
Here we develop a formalism for reversible ionic aggregation kinetics in an example concentrated electrolyte, building on previous equilibrium work of McEldrew and co-workers, and thermoreversible polymers and patchy particle...
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Mastering the Potential of Well-defined ML 1 L 2 Species in Asymmetric Catalysis through Ligand Immobilization (ML het L hom ). Use in Highly Enantioselective Pd-catalyzed Spiroannulation

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01392A, Edge Article

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Maria Biosca, Pol De La Cruz-Sánchez, Jorge Faiges, Aitor Maestro, C. Oliver Kappe, Sándor B. Ötvös, Miquel A. Pericas, Oscar Pamies, Montserrat Diéguez
Catalytic complexes involving different monodentate ligands coordinated to the same metal center offer considerable interest towards the development of new processes and the improvement of the characteristics of known ones....
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Methyl-Induced Ring-Locking Strategy for Concentration-Independent MR-TADF Emitters toward High-Performance OLEDs with BT. 2020 Blue Gamut

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC02303G, Edge Article

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Gaoyu Li, Yuyuan Wang, Bo Wu, Jinkun Bian, Haozhi Xie, Zhiwei Ma, Hui Dai, Zhan Yang, Xiangyu Ge, Zhenguo Chi
Realizing deep-blue multi-resonance thermally activated delayed fluorescence (MR-TADF) emitters that simultaneously offer high efficiency and resistance to aggregation-caused quenching (ACQ) remains formidably challenging, severely limiting their practical application in BT.2020-compliant...
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Tetraphenylborate-Based Anionic Metal−Organic Framework as an Efficient Single-Ion Conductor for Solid-State Sodium Battery

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC03302D, Edge Article

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Xiaoxin Liu, Zhiwei Lu, Qianyi Zhao, Shujun Li, Jie Zhang, Xuenian Chen, Qingchun Xia
Rechargeable sodium batteries (RSBs) have emerged as a promising contender in the post-lithium electrification era. However, their applications are often complicated by their inherent reactivity with flammable liquid electrolytes, which...
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eMALDI MS and oligonucleotide analysis

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01849A, Edge Article

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Manoj Perera, Yipeng Yin, Reed Arneson, Fakhira Razzaq, Rohith Awasthy, William Wittstock, Yinan Yuan, Shiyue Fang
Enhanced matrix assisted laser desorption ionization mass spectrometry (eMALDI MS), in which desorption and ionization is enhanced by heat and volatiles from decomposition of additives, enables analysis of longer oligos and increases salt tolerance.
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Direct arylation polymerization of electron-rich arenes with polar-group tolerance enabled by ligand-coordination tuning

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00984K, Edge Article

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Xilin Pei, Wei Wu, Yanlu Sun, Quan Yang, Jianan Weng, Shuhua Zhang, Zhi Geng, Bo Zhu
Ligand EDS controls C–H activation and polar-group tolerance in ligand-tuned DArP of polar-functionalized EDOTs. Weak donors promote Pd–C formation; strong donors favor Pd-phosphine coordination over off-cycle species. Moderate ligands balance effects for optimal polymerization.
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Superprotonic conductivity in crystalline and amorphous framework materials under anhydrous conditions

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02080A, Review Article

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Nattapol Ma
From channel-aligned MOFs/COFs to amorphous coordination polymer glasses, this review highlights how tunable framework materials enable fast anhydrous proton conduction and outlines design strategies for next-generation proton conductors.
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DeepPath: overcoming data scarcity for protein transition pathway prediction using physics-based deep learning

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC08253F, Edge Article

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Yui Tik Pang, Lixinhao Yang, Katie M. Kuo, James C. Gumbart
DeepPath combines generative learning with classical force fields to discover physically realistic protein transition pathways.
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Aromatic phosphonate-based luminophores: universal building blocks for ultralong room-temperature phosphorescence and multifunctional applications

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02475K, Edge Article

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Chunli Li, Zizhao Huang, Tao Li, Tengjiao Zhao, Lei Zhou, Zhenyi He, He Tian, Xiang Ma
By suppressing non-radiative transition, aromatic phosphonate-based luminophores were used to achieve efficient organic room-temperature phosphorescence. Stimulus-responsive, full-color tunability and multi-functional applications were realized.
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Manipulating excited-state dynamics through macrocycle positioning in a rotaxane for sensitive and discriminative methanol sensing

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00753H, Edge Article

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Yu Wang, Yalei Ma, Ruijuan Wen, Jing Li, Taihong Liu, Liping Ding, Rong Miao, Yu Fang
A supramolecular strategy for excited-state dynamics manipulation is demonstrated by controlling the distance between the macrocycle and the fluorophore within the rotaxane, which enables sensitive and discriminative methanol vapor sensing.
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Organic small-molecule-catalyzed carbonylation reactions

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02732F, Review Article

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Mao-Lin Yang, Le-Cheng Wang, Heifei Yang, Jiajun Zhang, Xiao-Feng Wu
This review examines organic small-molecule-catalyzed carbonylation, with a particular emphasis on N-heterocyclic carbene (NHC), oxygen, sulfur, selenium, nitrogen, and phosphine main-group species-based catalysts.
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Charge-regulated hepatic γ-glutamyltranspeptidase fluorescent probe: in vivo staging of Schistosoma infection

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02037B, Edge Article

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Xiaoxi Ma, Eryang Xie, Qiang Li, Chuyang Sun, Yongkang Yao, Chenxu Yan, Qianfu Luo, Zhiqian Guo, Wei-Hong Zhu
We developed a dicationic NIR fluorescent probe to address diagnostic limitations in schistosomiasis staging. With this strategy schistosomiasis severity can be distinguished, which enables non-invasive pathological identification and staging.
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Air-tolerant solar reforming of pre-treated biomass and plastics in viscous sustainable solvents

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01540A, Edge Article

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Dongseok Kim, Papa K. Kwarteng, Erwin Reisner
We report an air-tolerant solar reforming (SR) system for the valorisation of pre-treated biomass and plastic waste streams. This process operates in low O2-diffusivity solvents such as the robust deep...
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Artificial recombinant high-density protein nanocarriers for precision drug delivery

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC09151A, Review Article

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Wenpan Li, Nan Jia, Mengwen Li, Yanhao Jiang, Jianqin Lu
Chemically programmable reconstituted HDL nanocarriers for drug delivery.
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Electron transfer from singlet fission dimers: possibilities and limitations

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00259E, Edge Article

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Sree Chithra, Corentin Pigot, Claire Tonnelé, Ashley J Redman, Sabine Richert, David Casanova, Victor Gray
Photocatalytic production of H₂ or hydrocarbons requires multiple electrons, and therefore the absorption of multiple photons and accumulation of photoexcited charges. Alternatively, multiexciton generation (MEG) could loosen this requirement. Despite...
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Iron-mediated Reactions of gem-Dihaloalkanes with α,β-Unsaturated Carbonyl Compounds

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01614F, Edge Article

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Guangshen Wang, Jing Yao, Jianwei Liu, Tiantian Zhang, Xue Cheng, Li Li, Man-Yi Han, Baosheng Li
The ability to harness divergent reactivity and selectively dictate product outcomes from simple precursors has been a longstanding challenge in organic chemistry especially in radical chemistry. Herein, we developed a...
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A Unified Cobalt-Electrocatalytic Platform for Enantio- and Stereo-selective C−H and C−F Functionalization of gem-Difluoromethylene Allenes

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC02228F, Edge Article

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Cai Jiating, Xinyu Gao, Chuitian Wang, Yang Li, Xiaoxin Tong, Linzai Li, Shi Qin, Mingkai Yang, Qixin Li, Wei Wei, Lei Ma, Mei Wang, Si-Yan Liao, Yugang Huang, Xin Zhao, Shengdong Wang, Zhi Zhou, Hui Gao, Wei Yi, Zhongyi Zeng
While the merger of electrochemistry with enantioselective C−H functionalization has opened new avenues for assembling valuable chiral architectures, the simultaneous cleavage of strong C−H and C−F bonds via asymmetric electrocatalysis...
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Recent progress on Ni-catalysed alkyl-alkyl cross-coupling enabled by asymmetric hydrofunctionalization of alkenes

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00960C, Review Article

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Jiao He, Perla Bharath Kumar, Yu-Long Li, Qiong Yu, Wei Shu
The construction of saturated stereogenic centers, which are of significance in cutting-edge fields such as pharmaceutical research and materials science, represents a fundamental objective in organic synthetic chemistry. In this...
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Sterically controlled 5-exo-dig cyclization enables synthesis of non-benzenoid polycyclic aromatic hydrocarbons with intriguing (anti)aromaticity and diradical properties

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00121A, Edge Article

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Liangliang Chen, Zhichun Shangguan, Tianyu Shi, Liyuan Qin, Yiyun Zeng, Qingqiu Zhu, Jin Chen, Junhong Liang, Wentao Miao, Yurong He, Xiaosong Qiu, Xunchang Wang, Deqing Zhang, Renqiang Yang
A modular synthetic strategy based on sterically controlled 5-exo-dig cyclization enables the construction of stable non-benzenoid PAHs featuring indacene, pentalene, and azulene motifs, exhibiting tunable (anti)aromaticity and diradical character.
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Photo- and thermo-responsive complementary metal coordination for the construction of supramolecular polymers

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02381A, Edge Article

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Shenghui Rao, Yuzhen Wang, Ju-An Zhang, Liqing Li, Shaoyu Li, Linlin Liu, Yu Xie, Hui Li, Wei Tian
This study investigated the photo- and thermo-responsive modulation of terpyridine-based complementary metal coordination, as well as synergistic effects between different complementary coordination motifs.
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De novo construction of C–O axial chirality via cobalt-catalyzed atroposelective C–H activation/annulation

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02299E, Edge Article

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Yanbo Zhang, Yichao Xie, Baicheng Guo, Yingchao Dou, Dandan Yang, Jun-Long Niu
An unprecedented de novo synthetic strategy for the construction of C–O axially chiral aryl-heterocyclic ethers was developed via a cobalt-catalyzed asymmetric C–H activation/annulation of arylamides with rationally designed phenylethynyl ethers.
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Breaking the limit – synthesis and properties of p-amino-triazatriangulenium, the most stable carbenium ion

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01535B, Edge Article

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Marko H. Nowack, Gennaro Pescitelli, Arianna Lanza, Bo W. Laursen
Highly stabilized tris(dialkylamino)-triazatriangulenium (A-TATA⁺) and tris(methoxy)-triazatriangulenium (MeO-TATA⁺) carbenium ions have been synthesized and characterized as emissive dyes. A-TATA⁺ is the most stable carbenium ion reported to date.
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Li diffusion and migration are influenced differently by co-solvents in polymer electrolytes based on poly(ε-caprolactone) and poly(ethylene oxide)

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00596A, Edge Article

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Simon Buyting, Monika Schönhoff
Li-coordinating co-solvents have opposite influence on ion diffusion in PCL- and PEO-based polymer electrolytes, while ion migration remains unaffected.
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Chalcogen bonding-directed photoresponsive helix from azo-fused H-bonded arylamide foldamers

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC10108E, Edge Article

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Chuan-Zhi Liu, Chi Zhang, Hua-Shuo Zheng, Liu-Xin Luo, Shuang-Shuang Hou, Song-Hao Guo, Meng-Ge Zhang, Xin-Yao Peng, Liang Xu, Bin Zhai
The self-assembly of a photoresponsive supramolecular helix orthogonally guided by dual intermolecular Se⋯N chalcogen bonding and intramolecular hydrogen bonding.
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Efficient red circularly-polarized phosphorescence from pyrene derivatives mediated by locked axial chirality scaffold

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01341D, Edge Article

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Wenbin Huang, Chenlong Wei, Meng Wang, Qian Zhang, Zikai He
The work presents a strategy to achieve circularly polarized fluorescence and phosphorescence with enhanced intersystem crossing and amplified the dissymmetry factor of pyrene derivatives by employing locked axially chiral binaphthalene.
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Revealing transport kinetics for efficient electrochemical conversion of captured CO2 in amine solutions

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00859C, Edge Article

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Zhihui Lv, Kang Liu, Chun-Qing Yin, Lin Du, Min Liu, Xin-Ming Hu
This work identifies bicarbonate as the reactant for electrochemical conversion of captured CO₂ in divergent amine solutions, and establishes mass transport manipulation via amine design as a key strategy for achieving high conversion efficiency.
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Responsible chemistry for a changing world: IUPAC's guiding principles

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC08844E, Perspective

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J. Garcia-Martinez, Peter G. Mahaffy, Mark C. Cesa, Mei-Hung Chiu, Jonathan E. Forman, Mary J. Garson, Richard M. Hartshorn, Tanja Junkers, Leah McEwen, Akiko Nakamura, Daniel O. Reddy, Marvadeen A. Singh-Wilmot, Christine M. Straut Langlinais, Supawan Tantayanon, Rylee E. Van't Land
IUPAC has developed a set of guiding principles for the responsible practice of Chemistry worldwide that embrace scientific excellence and nurture a shared commitment to ethical and responsible conduct that is aligned with world needs.
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Promoting effect of nickel-chromium hydroxide on nickel phosphide nanosheets for efficient hydrogen production coupled with sulfion degradation

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02309F, Edge Article

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Xiaojun Wang, Jieting Li, Xinyu Zhu, Zehua Xu, Shuixiang Xie, Shutong Chen, Yuxuan Wan, Guangyu Zhang, Mingzheng Ge, Wei Zhang, Chao Wang, Rui-Qing Li
We developed Ni₂P/NiCr(OH)₂ nanosheets to simultaneously catalyze hydrogen evolution and sulfion oxidation reactions, which realize energy-saving hydrogen generation and sulfion upgradation to valuable elemental sulfur.
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Dimensional engineering in chiral layered hybrid perovskites for high-anisotropy self-powered circularly polarized light detection

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00286B, Edge Article

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Wan Luo, Qianxi Wang, Xiaoqi Li, Fen Zhang, Yan Fu, Yikun Fu, Xiaoyu Zhang, Guifu Zhang, Xitao Liu, Junhua Luo
Chiral perovskites have emerged as a highly promising family of materials for circularly polarized light (CPL) detection, owing to their unique combination of structural chirality and remarkable optoelectronic performance.
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Oscillator–qubit generalized quantum signal processing: a case study of the uracil cation vibronic model

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC09606E, Edge Article

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Jungsoo Hong, Seong Ho Kim, Seung Kyu Min, Joonsuk Huh
Oscillator–qubit generalized quantum signal processing (OQ–GQSP) enables direct vibronic dynamics simulation of the uracil cation, compiling efficient nonadiabatic propagation on hybrid oscillator–qubit quantum processors.
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Instability of PCN-224(Fe) during the oxygen reduction reaction; metal–organic framework electrocatalysts may have an Achilles heel

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01428C, Edge Article

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Dana Rademaker, Roy Maas, Stefania Tanase, Hongrui Kang, Jan P. Hofmann, Dennis G. H. Hetterscheid
Redox moieties that serve a dual role as electron transport hub and as a catalytic site represent a major stability concern in electrocatalysis featuring metal–organic frameworks.
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Bridging Lewis acidic antimony centers with electron-withdrawing carborane cages

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00316H, Edge Article

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Victoria P. Rubio, McKinley H. Durham, Matthew Scurria, Tyler A. Kerr, Osvaldo Gutierrez, Alexander M. Spokoyny
We show that C-bound carboranes can serve as effective alternatives to perfluorinated arenes for the generation of Lewis acidic Sb(V) species.
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18F-Labelling of (Hetero)aryl Halides via Sequential Miyaura Borylation/Copper-Mediated Radiofluorination

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01625A, Edge Article

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Abdias N Noel, Samuel G Greco, Mami Horikawa, Taylor Spiller, Diana L Nichols, Jason A Witek, Allen F Brooks, Peter J. H. Scott, Melanie S Sanford
This Article describes the development of a mild, general, and highly reproducible method for the radiofluorination of (hetero)aryl iodide, bromide, and chloride substrates. This transformation proceeds via sequential Pd-catalysed Miyaura...
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Inducing a chiral twist in achiral porphyrins: tailoring molecular interactions for circularly polarized luminescence from chiral microflowers

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D5SC09327A, Edge Article

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Arunima Cheran, Betsy Marydasan, Saikat Das, Hrishikesan Kalpakassery Pattam, Jatish Kumar
A facile and novel strategy for induction of chirality in achiral porphyrins through the synergistic use of chiral mandelic acid and Zn(II) ions is reported. The nanostructures exhibit chiral luminescence in both solution and solid states.
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Unravelling Intrinsic Thermal Conduction Mechanism through Phonon Transport Pathway Engineering of Long-Range Ordered Block Copolymers

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01804A, Edge Article

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Kuan Zhang, Junliang Zhang, Jiahao An, Junwei Gu
Highly thermally conductive polymers are playing essential roles in various electronics-related fields. However, the mechanism underlying thermal conduction remains hitherto elusive. Herein, the intrinsic thermal conduction mechanism of polymers was...
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Total and Engineered Biosynthesis of Cinatrins: Inhibitors of Phospholipase A2 and Squalene Synthase

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00660D, Edge Article

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Henrike Heinemann, Nick Gerlach, Eric Kuhnert, Jennifer Gerke, Bart Verwaaijen, Jorn Kalinowski, Marc Stadler, Russell Cox
An alkyl citrate biosynthetic gene cluster (ctr) was identified from 47 members of the fungal family of Hypoxylaceae by genome mining. The Hypomontagnella monticulosa MUCL 54604 ctr cluster was deployed...
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Recent advances in VAT photopolymerization additive manufacturing of battery electrodes: towards high-resolution 3D-printed batteries

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01385F, Review Article

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Sima Lashkari, Antonio Dominguez-Alfaro, David Mecerreyes
Additive manufacturing of battery enables a more versatile battery form factor and design.
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Modular assembly of chiral biaryl phosphoramidite (BPA) libraries by nickel catalysis

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00358C, Edge Article

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Xi Zhang, Jingyi Bai, Yue Zhao, Minyan Wang, Zhuangzhi Shi
A P(III)-directed C–H arylation method has been established, enabling the modular assembly of biaryl phosphoramidite (BPA) libraries that demonstrated exceptional efficacy in palladium-catalyzed asymmetric reactions.
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Supramolecular Assembly Strategy of Multinuclear Platinum(II) Complexes for Proof-of-Concept Detection and Extraction of Perfluorohexanoic Acid

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00989A, Edge Article

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Nicholas Chun-Ming Yeung, Zhen Chen, Ziyong Chen, Eric Ka-Ho Wong, Vivian W. W. Yam
Wide applications of per-/poly-fluoroalkyl substances (PFAS) in manufacturing fluorinated-polymer coatings and products pose serious health and environmental threats due to their highly chemical robustness. The development of efficient sensors for...
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π-Aggregation-free, fused perylene pentamers: synthesis, narrowband far-red to near-infrared emission, and chiroptical properties

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00676K, Edge Article

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Qifeng Zhou, Lin-Tao Bao, Rui Liu, Zhitao Sun, Zhuolin Ye, Liuying Jiao, Wei Fan, Ya Zou, Hai-Bo Yang, Jishan Wu
π-Aggregation-free, fused perylene pentamers were synthesized in one pot, showing high solubility and fluorescence. Isomeric and π-extension tuning enables visible to pure far-red to NIR emission with narrow bandwidths and enhanced CPL brightness.
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Symmetry-directed complex tessellation of irregular polygons from a single molecular precursor

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00180G, Edge Article

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Wenya Zhai, Zengfu Ou, Ye Chen, Haoyuan Zang, Donghui Guo, Jingcheng Li
Constructing molecular superlattice tessellations from irregular hexagonal building blocks via symmetry-driven dimerization (C₂) or hexamerization (C₆) pathways.
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Resolving the inner versus outer component of the 5 f radial wavefunction in the early actinides

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC02413K, Edge Article

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Nathan M Alcock, Myron Huzan, Timothy Burrow, Myrtille O.J.Y Hunault, Christelle Tamain, Matthieu Autillo, Thomas Dumas, Michael Lloyd Baker
Actinide chemistry is largely defined by 5f orbital behaviour, but experimental measurements of their role in bonding are scarce, despite their importance for understanding chemical reactivity. Here, we demonstrate that...
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Electrocatalytic methane oxidation via integrated design of mechanism, microenvironment, and mass transfer

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC00875E, Review Article

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Hui Jian Zhang, Xiao-Tong Wang, Luxiao Zhou, Jiguang Deng, Zhong-Wen Liu, Zhao-Qing Liu
Electrocatalytic methane oxidation (EMO) offers a promising approach by utilizing renewable electricity to drive electrontransfer reactions, enabling C-H bond activation and transformation into value-added chemicals at ambient temperature and pressure...
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Multifunctional Conductive Dressings for Wound Healing Support

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01545J, Review Article

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Jingwen Jadranka Yang, Lisa I Pilkington, Jadranka Travas-Sejdic
Chronic and non-healing wounds, characterised by persistent inflammation, recurrent infections and impaired angiogenesis, remain a significant clinical and socioeconomic burden. Conductive polymers (CPs) have emerged as promising materials for actively...
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Slow Cooling and Efficient Extraction of Hot Carriers in Perovskite Films via Engineering Trap-Mediated Relaxation Channel

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01780K, Edge Article

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Xinlei Zhang, Jing Leng, Qi Sun, Qingshun Dong, Xinyu Tong, Yu Song, Yan Xu, Shengye Jin, Wenming Tian
Long-lived hot carriers (HCs) are highly desired for HC photovoltaics, but achieving slow HC relaxation is challenging because strong electron-phonon interaction typically drives rapid thermalization. Herein, we investigate the influence...
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Borane catalysed annulative sulfenylation of internal alkynes: towards the synthesis and study of fused heterocycles

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01123C, Edge Article

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Sampurna Das, Milan Pramanik, Johannes Westphäling, Abhishek Kumar Gupta, Thomas Wirth, Niklaas J. Buurma, Eli Zysman-Colman, Mu-Hyun Baik, Rebecca L. Melen
This work presents an amenable and efficient B(C₆F₅)₃-catalysed route for the construction of sulfur-containing heterocycles via thiirenium-ion intermediates.
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Synthesis, characterization, and imidogen photochemistry of a hydrazoic acid adduct of Rh2

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02258H, Edge Article

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Arpan Paikar, Phong Thai, Matthew T. Figgins, Bodhisattwa Mandal, Matthew J. Lekas, Joseph H. Reibenspies, Gerard P. Van Trieste, David C. Powers
Synthesis of the first crystalline transition metal complex of hydrazoic acid provides a platform to photogenerate metal imidogen complexes proposed in metal-cataylzed NH-transfer.
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Lucigenin: a strongly oxidizing dicationic photocatalyst for the direct azolation of arenes

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC02111E, Edge Article

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Alexandra Matei, Baptiste Roure, Xiaobing Chen, Sebastian B. Beil, Ben L. Feringa
Lucigenin, a widely used fluorescent probe in biology, was used for the first time in photocatalysis to achieve the direct C–H azolation of arenes.
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Free Energy Relationship Analysis for Temperature Dependence of Hydride Kinetic Isotope Effects of NADH/NAD+ Model Reactions: Implication for Barrier Compression by Enzyme Dynamics

Chem. Sci., 2026, Accepted Manuscript
DOI: 10.1039/D6SC01847E, Edge Article

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Ava Austin-Kloppe, Nicholas Degroot, Bikram Dhakal, Jessica Sager, Lauren Phan, Seyedmehrad Poormoghim, Yun Lu
Observed shift from temperature(T)-independence of hydrogen kinetic isotope effects (KIEs) in wild-type enzymes to T-dependence of KIEs in enzyme mutants has been explained as evidence for a role of protein...
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Beyond static paradigms: defect dynamic evolution and advanced applications in water electrolysis

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01899H, Review Article

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Xiaojun Wang, Huilin Zhao, Lei Li, Weiping Xiao, Guangrui Xu, Guangying Fu, Lei Wang, Zexing Wu
This review comprehensively analyzes defect engineering in electrocatalysis, covering defect classification, synthesis, dynamic evolution, and advanced applications in water electrolysis.
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An extrinsic enzyme-activatable fluorescent probe for high-contrast tumor imaging

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00484A, Edge Article

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Yifang Guo, Yuwei Du, Liru Heng, Huimin Miao, Chen Chen, Qiang Zhang, Jiayi Wang, Yige Shan, Zhang Chen, Li Li
Malignant tumors pose a major threat to human health, and the effectiveness of treatment largely depends on accurate early diagnosis and complete resection.
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Highly Cα-regio-, enantio- and diastereoselective Mukaiyama-type annulation of siloxyfurans: stereodivergent synthesis of multi-stereogenic tricyclic γ-lactones

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01491G, Edge Article

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Lifei Gan, Zi-Qing Li, Tao Chen, Xuanchen Wan, Junyang Zhang, Jiangtao Ren, Ming Jiang, Penglong Cao, Jinhai Huang, Yu-Hua Deng, Fangzhi Peng, Run Tian, Yingcheng Wang, Zhihan Zhang, Zhihui Shao
We disclose a catalytic asymmetric Mukaiyama/lactonization reaction of 2-siloxyfurans with outstanding Ca-selectivity, enabling achiral Lewis acid-directed diastereodivergent access to important multi-stereogenic γ-lactones.
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Engineering hydrophobic covalent organic frameworks for electroreduction of nitrate to ammonia

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01645F, Edge Article

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Fuzhen Li, Huan Lin, Chunying Chen, Li-Lin Tan, Dawei Wang, Cunyuan Zhao, Li Zhang, Cheng-Yong Su
Hydrophobic bimetallic covalent organic frameworks of Pd-PCOF(Cu₃) were synthesized via a molecular engineering strategy and displayed synergistic catalysis in nitrate electroreduction to ammonia.
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Turn-on fluorescence switching and radical formation in a dual-functional negative photochromic dimethyldihydropyrene

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01682K, Edge Article

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Sariful Molla, Samyadeb Mahato, Avinash Kumar Ray, Subhajit Bandyopadhyay
We have demonstrated fluorescence switching in a negative photochromic dimethyldihydropyrene–triphenylamine system. The same molecular system enables light-driven generation of an air-stable radical cation.
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Stereoselective hydrogen isotope exchange on nicotinamide cofactors through flavoenzyme microscopic reversibility

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01003B, Edge Article

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Christopher W. Otun, Michael Yuen, Harry J. Spacey, Carlo Bawn, Matthew J. Cliff, Francesco Falcioni, Ryan A. Bragg, Charles S. Elmore, Sam Hay, Jack S. Rowbotham
Redox neutral stereoselective hydrogen isotope exchange on NAD(P)H is shown by a panel of flavoenzymes. This activity enables simple preparation of isotopologues of these important biological cofactors for use in synthesis and mechanistic studies.
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Correction: Recent advances in MOF-based single-atom photocatalysts for CO2 to solar fuel conversion under sunlight irradiation

Chem. Sci., 2026, 17,8803-8803
DOI: 10.1039/D6SC90091G, Correction

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Adnan Majeed, Minh-Khoa Duong, Van-Duc Nguyen, Trong-On Do
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Correction: Theoretical insights into site-specific heavy-atom effects on MR-TADF emitters: modulation of spin–orbit coupling and color purity

Chem. Sci., 2026, 17,8804-8805
DOI: 10.1039/D6SC90086K, Correction

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Shi-Jie Ge, Jian-Rong Wu, Zuo-Quan Jiang
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Ultralong organic room-temperature phosphorescence of tetraphenylene via lactose functionalization and chromophore isolation

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01359G, Edge Article

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Xin Niu, Mingxing Chen, Yuan Zhang, Guang-jian Liu, Su-Hang Qian, Hui Zhang, Jia-Qing Jiang, Hongwei Tan, Guo-wen Xing
A water-soluble amorphous nonplanar tetraphenylene system with ultralong room-temperature phosphorescence is achieved via lactose functionalization and a core isolation strategy, highlighting its utility in advanced information encryption.
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Regulation of local chemistry in O3-type layered oxide cathodes for practical sodium-ion batteries

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC01783E, Edge Article

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Tongtong Huo, Qian Yang, Genliang Yu, Mingyue Li, Xuejie Bai, Ting Lv, Xiaobo Zhang, Jie Xu, Kai Liu, Xunzhu Zhou, Xin Tan, Lin Li, Kaixiang Lei, Shijian Zheng
A versatile cation–anion dual-site high-entropy doping strategy is proposed to modulate the local chemistry of O3-type layered oxide cathodes, furnishing a robust foundation for advancing cathode materials for practical SIBs.
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Black-box data: a new paradigm for biomedicine in the AI era

Chem. Sci., 2026, 17,8327-8344
DOI: 10.1039/D6SC01189F, Perspective

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Luca Naef, Michael Bronstein
“Black-box” data sources prioritize machine learning consumption by moving away from tradeoffs optimized for human-centric consumption, yielding orders of magnitude higher throughput. Our paper outlines seven design strategies to achieve this.
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How solvent activity and solute solvation control electrode potentials: quantitative insights from Li+ insertion into TiO2

Chem. Sci., 2026, Advance Article
DOI: 10.1039/D6SC00393A, Edge Article

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Ludivine K/Bidi, Tom Rocca, Lucie Chen, Andrea Gutierrez Schindler, Benoît Limoges, Véronique Balland
A thermodynamic framework using a modified Nernst equation to quantitatively links electrode potentials to electrolyte concentration via salt/solvent activities and salt hydration number. Demonstrated for Li⁺ insertion into TiO₂ from aqueous LiCl.
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Electronic structure manipulation in electrocatalysis: mechanisms and design principles

Chem. Sci., 2026, 17,8372-8395
DOI: 10.1039/D5SC08985A, Review Article

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Hangkai Shi, Yuanduo Li, Shuyi Pang, Aixin Ma, Jianping Lai, Lei Wang
This review addresses four critical electronic-level challenges in electrocatalysis. It examines design strategies. Advanced theoretical methods are highlighted.
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Atomic-level engineering of single-atom catalysts for selective C–C coupling in CO2 hydrogenation to ethanol

Chem. Sci., 2026, 17,8432-8452
DOI: 10.1039/D6SC01691J, Review Article

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Wenyu Zheng, Yiming Liu, Xiaohai Zhang, Shengjie Bai, Aobing Li, Kelun Jiang, Feng Wang, Ya Liu, Yubin Chen, Shaohua Shen
This review explores single-atom catalysts for CO₂-to-ethanol conversion, focusing on atomic-level design principles that enhance C–C coupling selectivity and activity to enable sustainable carbon utilization and renewable fuel production.
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Recent advances in MOF-based single-atom photocatalysts for CO2 to solar fuel conversion under sunlight irradiation

Chem. Sci., 2026, 17,8396-8431
DOI: 10.1039/D6SC00691D, Review Article

Open Access

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Adnan Majeed, Minh-Khoa Duong, Van-Duc Nguyen, Trong-On Do
Rationally designed MOF-based single-atom catalysts enable efficient and selective solar-to-fuel CO₂ conversion.
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Solvation-driven interphase engineering and mechanical failure pathways in large-scale anode-free lithium metal batteries

Chem. Sci., 2026, 17,8453-8471
DOI: 10.1039/D6SC00025H, Edge Article

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Nattanon Joraleechanchai, Nuttida Matkhaw, Thitiphum Sangsanit, Worapol Tejangkura, Montree Sawangphruk
Anode-free lithium–metal batteries promise ultrahigh energy density but remain limited by unstable interfaces and safety concerns.
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Theoretical insights into site-specific heavy-atom effects on MR-TADF emitters: modulation of spin–orbit coupling and color purity

Chem. Sci., 2026, 17,8493-8503
DOI: 10.1039/D6SC00582A, Edge Article

Open Access

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Shi-Jie Ge, Jian-Rong Wu, Zuo-Quan Jiang
In multi-resonance thermally activated delayed fluorescence (MR-TADF) materials, the introduction site of heavy atoms exhibits an antagonistic effect on color purity and spin–orbit coupling.
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Molecular engineering of metalloporphyrins and phthalocyanines for homogeneous and heterogeneous CO2 electroreduction

Chem. Sci., 2026, 17,8345-8371
DOI: 10.1039/D5SC07983G, Review Article

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Aakash Santra, Arnab Ghatak, Zhiyuan Chen, Jing Shen, Joost Helsen, Yuvraj Birdja, Ally Aukauloo, Chanjuan Zhang
This review summarizes advances in CO₂ electrocatalysis, from homogeneous to heterogeneous systems, with emphasis on hybrid molecular–metallic co-catalysts that drive improved activity, selectivity, and overall catalytic performance.
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Triethanolamine-activated imine-linked covalent organic frameworks for highly efficient NADH generation

Chem. Sci., 2026, 17,8787-8794
DOI: 10.1039/D6SC01309K, Edge Article

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Xiaoyu Li, Rui Liu, Han Cao, Chuanyin Tang, Guancheng Hua, Yingxu Hu, Xiangjiang Fan, Yongqing Xia, Shengjie Wang
We present a reversible activation mechanism of imine-linked COFs under non-acidic conditions with triethanolamine under light irradiation, in which TEOA functions as both an electron and proton donor.
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Promoted hydrogen activation and spillover over Pt/Co3O4 by facet engineering of Co3O4 for enhanced catalytic hydrogenation

Chem. Sci., 2026, 17,8753-8759
DOI: 10.1039/D5SC09402J, Edge Article

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Hui Yun, Jiao Feng, Wanying Peng, Mi Xiong
The (111) facet-induced electron-rich Pt nanoparticles on Co₃O₄ accelerate both H₂ activation and hydrogen spillover dynamics, leading to a superior turnover frequency (TOF) in catalytic hydrogenation.
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Ring-opening decarbonylative C(sp3)–C(sp3) cross-electrophile coupling of cyclic imides with unactivated alkyl chlorides

Chem. Sci., 2026, 17,8479-8485
DOI: 10.1039/D6SC00815A, Edge Article

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Niklas J. Lentelink, Peter M. F. Pânzar, Nathalie A. V. Rowlinson, Bill Morandi
Selective nickel-mediated endocyclic N–C(O) activation establishes cyclic imides as competent electrophiles in decarbonylative C(sp³)–C(sp³) cross-electrophile coupling with unactivated alkyl chlorides.
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Combined electrodeposition and electropolymerization method to produce surface-bound polystyrenyl NHC thin films

Chem. Sci., 2026, 17,8472-8478
DOI: 10.1039/D6SC00603E, Edge Article

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Jessica L. Bosso, Justin T. Lomax, Garima Garg, Wai-Tung Shiu, Jordan N. Bentley, Matthew J. Turnbull, Monika R. Snowdon, James J. Noël, Cathleen M. Crudden, Joe B. Gilroy, Paul J. Ragogna
Polymeric N-heterocyclic carbene (NHC) films offer a promising strategy for generating durable protective coatings on metals.
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Simulating enzyme catalysis with electrostatically embedded machine learning potentials

Chem. Sci., 2026, 17,8542-8556
DOI: 10.1039/D6SC01156J, Edge Article

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Valentin Gradisteanu, Elliot W. Chan, Lester Hedges, Meritxell Malagarriga, Rolf David, Miguel de la Puente, Damien Laage, Iñaki Tuñón, Marc W. van der Kamp, Kirill Zinovjev
Enzyme catalysis can be simulated accurately and efficiently by coupling machine-learned potentials trained on gas-phase data to the environment (ML/MM) using electrostatic machine-learning embedding (EMLE).
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Photoinduced intramolecular S-α-C(sp3)–H functionalization enabled by an electron donor–acceptor complex-Mediated radical relay

Chem. Sci., 2026, 17,8683-8691
DOI: 10.1039/D6SC01281G, Edge Article

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Tiantian Xu, Ran Hong, Tong Lu, Denghua Zhu, Jiong Yu, Min Wang, Pinhua Li
We describe a consecutive reaction of 2-alkynylthioanisoles and 4-cyanopyridine enabled by EDA complex photoactivation, which facilitates the sequential S-α-C(sp³)–H bond activation, cyclization and radical coupling under mild conditions.
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Computational study of the effect of Lewis base additives and molecular spin state in SmI2-chemistry

Chem. Sci., 2026, 17,8744-8752
DOI: 10.1039/D5SC08336B, Edge Article

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Song Yu, Ciro Romano, David J. Procter, Nikolas Kaltsoyannis
Computational study reveals the role of Lewis bases in SmI₂ chemistry, from tuning reducing power and modulating single-electron transfer to shaping reaction potential energy surfaces.
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Amino acid appended supramolecular self-associating amphiphiles demonstrate dual activity against both MRSA and ovarian cancer

Chem. Sci., 2026, 17,8567-8579
DOI: 10.1039/D5SC03376D, Edge Article

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Precious I. A. Popoola, Thomas L. Allam, Rebecca J. Lilley, Chandni Manwani, Olivia B. Keers, Junyang Tan, Kylie Yang, Yifan Long, Ewan R. Clark, Lisa J. White, Kira L. F. Hilton, Jennifer Rankin, Jennifer Baker, Charlotte Bennett, Hollie B. Wilson, Evelyn R. Morton, Alvaro Keskküla, Bethany Martin, Christopher O'Connor, J. Mark Sutton, Charlotte K. Hind, Michelle D. Garrett, Cally J. E. Haynes, Jennifer R. Hiscock
Novel amphiphiles target cell membranes, demonstrating biological efficacy against resistant S. aureus and ovarian cancer, with strong mechanistic and DMPK evidence for future therapeutic development.
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Spin-regulated d–p hybridization enables high energy density and wide temperature operation of Na3V2(PO4)2O2F-type cathodes for sodium-ion batteries

Chem. Sci., 2026, 17,8638-8650
DOI: 10.1039/D6SC00912C, Edge Article

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Qiang Fu, Qin He, Fangxiang Song, Xianquan Ao, Hanxiao Liu, Yang Cao, Rong Li, Keliang Wang, Jing Li, Cuiqin Li, Yao Xiao
By dual-doping NVPOF with transition metals of different spin states and fluorine, the V 3d–O 2p bonding is adjusted to reduce the bandgap. This simultaneously enhances electronic and ionic conductivities, improving the high rate capability.
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Two-dimensional Pd–C bonded organometallic framework with dynamic packing transformations

Chem. Sci., 2026, 17,8726-8732
DOI: 10.1039/D5SC08775A, Edge Article

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Jong-Yeong Jung, Jaewook Kim, Jintaek Gong, Dongwook Kim, Hee-Seung Lee, Hyunjoon Song
C–H activation enables terephthalate to act as an organometallic ligand, stabilizing Pd atoms and yielding Pd–C bonded PdOF-1.
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Fully protected pyrophosphates via phosphorobromidates for the synthesis of biopolymers

Chem. Sci., 2026, 17,8630-8637
DOI: 10.1039/D6SC01119E, Edge Article

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Sven Wijngaarden, Femke L. A. M. van der Heijden, Koen J. Rijpkema, Bob van Puffelen, Nico J. Meeuwenoord, Danicia Ramcharan, Gijsbert A. van der Marel, Jeroen D. C. Codée, Herman S. Overkleeft, Dmitri V. Filippov
A P(V)–P(V) coupling strategy using phosphorbromidate electrophiles, enables the solid-phase synthesis of fully protected pyrophosphates. This methodology provides synthetic access to defined ADPr fragments of unprecedented length.
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Red-light photoredox catalysis with bridged fluorescein derivatives: mechanistic insights and application to fluoride-responsive photopolymerization

Chem. Sci., 2026, 17,8604-8621
DOI: 10.1039/D6SC01311B, Edge Article

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Dokyeong Lee, Hoyun Kim, Byunghyuck Jung, Sung Ho Yang, Hong-In Lee, Jungkyu K. Lee
We demonstrated bridged fluoresceins (BFLs) as a class of metal-free red-light photocatalysts that feature structurally tunable and switchable activity in aqueous solutions.
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Rational design of a polyphenyl octacarboxylate HOF for highly selective separation of benzene over cyclohexane

Chem. Sci., 2026, 17,8772-8779
DOI: 10.1039/D5SC10068B, Edge Article

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Biying Liu, Ying Wang, Miao She, Tianfu Liu, Manxin Luo, Yongxin Xie, Defei Liu, Ziyi Du, Liyun Huang, Wenbing Yuan
A rationally designed octacarboxylate-based HOF exhibits exceptional benzene/cyclohexane separation, with an adsorption capacity of 3.9 mmol g⁻¹ and a selectivity of 16.9.
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Polymorphism-driven coordination geometry engineering for boosting nitrate electroreduction in Cu-pyrazolate chains

Chem. Sci., 2026, 17,8521-8527
DOI: 10.1039/D5SC09385F, Edge Article

Open Access

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Zhanning Liu, Shanna An, Qingzhong Xue, Jian Tian
Coordination geometry-driven polymorphism in copper pyrazolates tailors Cu electronic structures, leading to highly efficient electrocatalytic nitrate reduction to ammonia with a faradaic efficiency of 93.3%.
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Directing structural transformation in gold(I)–carborane nanoclusters to unlock ultrafast hypergolic ignition

Chem. Sci., 2026, 17,8795-8802
DOI: 10.1039/D6SC01070A, Edge Article

Open Access

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Hao-Hui Xie, Wen-Jing Yang, Ze-Jian Li, Ying-Zheng Ren, Nian Si, Peng-Fei Liu, Yong-Xing Tang, Wen-Chao Zhang, Peng-Fei Cui
Two novel structural transformation routes in gold–carborane nanoclusters are elucidated, and the relationships between their structures and ignition properties are comprehensively discussed.
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Achiral benzoic acid appended helical polymers for the copper-catalyzed asymmetric Diels–Alder reaction and Michael addition with excellent enantioselectivity and recyclability

Chem. Sci., 2026, 17,8733-8743
DOI: 10.1039/D6SC01369D, Edge Article

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This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Qi-Hui Ti, Ming-Yang Mo, Run-Tan Gao, Na Liu, Zong-Quan Wu
One-handed helical polyisocyanides bearing achiral benzoic acid pendants were synthesized and utilized as chiral ligands, enabling highly active and enantioselective copper-catalyzed asymmetric Diels–Alder reactions and Michael additions.
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Engineering the interfacial water microenvironment to accelerate proton transfer for acidic oxygen evolution at high-potential

Chem. Sci., 2026, 17,8504-8512
DOI: 10.1039/D6SC01336H, Edge Article

Open Access

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Xiaolong Liang, Ke Xu, Hengkun Yu, Xu Ge, Zhiwen Liu, Xueliang Mu, Shaoke Zhang, Jake M. Yang, Jinxuan Liu
The heterostructure disrupts the interfacial H-bond network at high potentials, facilitating proton transfer and establishing it as a new key determinant of activity.
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Crystalline covalent organic polymer as an effective zincophilic protective layer to boost the performance of aqueous zinc-ion batteries

Chem. Sci., 2026, 17,8692-8700
DOI: 10.1039/D5SC08630B, Edge Article

Open Access

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Xin Wang, Yuchan Zhang, Lei Zhang, Qianfeng Gu, Qi Liu, Yang Ren, Chun-Sing Lee, Qichun Zhang
Single crystals of a 1D tetrathiafulvalene-based covalent organic polymer (CityU-51) serve as anode protective layer in aqueous Zn-ion batteries, achieving an ultra-long lifespan exceeding 6300 h at 1 mA cm² and over 6000 h at 30 mA cm².
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Stearic acid-modified PSMA-targeting peptide–drug conjugate for long-acting prostate cancer therapy

Chem. Sci., 2026, 17,8651-8661
DOI: 10.1039/D5SC08259E, Edge Article

Open Access

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Ziwen Qiu, Xiaorui Zheng, Shoumei Pan, Yingtao Zhong, Xiayun Chen, Xuejun Wen, Xin Chen, Shiying Li, Hong Cheng, Xiaoyuan Chen
Prostate-specific membrane antigen (PSMA)-targeting peptide–drug conjugates (PDCs) offer promise for the treatment of PSMA-positive prostate cancer, but their applications are limited by rapid clearance, poor pharmacokinetics, and low efficacy.
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Single stereocenter inversion of a cyclic tetrapeptide enables the detoxification of lead-exposed mice

Chem. Sci., 2026, 17,8557-8566
DOI: 10.1039/D5SC09201A, Edge Article

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Tagwa A. Mohammed, Luca Sauser, Erica Pedron, Yaël A. Hodel, Tadeáš Kalvoda, Francesco Prisco, Lubomír Rulíšek, Jason P. Holland, Michal S. Shoshan
Structure-guided optimization of a peptidic chelating agent, combining high Pb(II) affinity, selectivity, and in silico modelling, enables efficient in vivo Pb detoxification, including brain Pb reduction and selective urinary excretion.
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Efficient near-infrared-excitable quantum dot-based triplet–triplet annihilation upconversion with a record anti-Stokes shift via low coverage of mono-styryl-BODIPY ligands

Chem. Sci., 2026, 17,8595-8603
DOI: 10.1039/D6SC00714G, Edge Article

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This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Ran Li, Lin-Han Jiang, Lin Xi, Ming-Yu Zhang, Hong-Juan Feng, Dong-Xue Guo, Lili Hou, Ling Huang, Dai-Wen Pang
A mono-styryl-BODIPY ligand on PbS QDs achieves an upconversion efficiency of 16.8% ± 0.6% with only seven ligands per dot when rubrene is used as the annihilator. Furthermore, coupling this system with BPEA enables a significant anti-Stokes shift.
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Zr6O4(OH)4(O2C-t-Bu)12 precursor uncovers how modulators govern supersaturation, nucleation, and growth of UiO-66 nanocrystals

Chem. Sci., 2026, 17,8719-8725
DOI: 10.1039/D5SC08105J, Edge Article

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Jade M. Kemp, Jonathan S. Owen
Modulator controls supersaturation, low surface energy, and slow ripening.
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Low-valent Mo single atoms stabilized by electronegative oxygen coordination enable efficient water oxidation

Chem. Sci., 2026, 17,8670-8682
DOI: 10.1039/D6SC00877A, Edge Article

Open Access

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Yang Yang, Ji-Kai Li, Qian-Nan Yang, Yi-Bin Yang, Jian-Hua Meng, Lin Zhang, Ying-Dan Wu, Ke-Xiang Wang, Huan Chen, Zhi-Yuan Jiang, Rui Chao, Wei-Tao Wang, Xiao Ma, Zhao-Tie Liu
An oxygen-anchored, low-valent Mo single-atom catalyst, featuring a coordinately unsaturated Mo–O₃ motif, significantly enhances electrocatalytic oxygen evolution, enabling operation at an ultra-low overpotential.
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Hierarchical polar–nonpolar phase architecture enabling excellent lead-free capacitive energy storage

Chem. Sci., 2026, 17,8701-8711
DOI: 10.1039/D6SC00039H, Edge Article

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Qingqing Wu, Huajie Luo, Yuhang Hu, Yuhui Huang, Xiangwei Guo, Hubo Zhu, Haishan Xu, Shenglin Jiang, Tianyu Li, Bing Xie
A polar–nonpolar hierarchical phase architecture design has been proposed in BaTiO₃–Bi(Mg_0.5Ti_0.5)O₃-based dual-phase ceramics to significantly enhance dielectric energy storage performance.
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An increased throughput workflow to identify ion transport and membrane lysis agents for antimicrobial discovery

Chem. Sci., 2026, 17,8580-8594
DOI: 10.1039/D5SC09781A, Edge Article

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Kylie Yang, Caleb Marsh, Lisa J. White, Fergus W. Molyneux, Thomas L. Allam, Precious I. A. Popoola, Olivia B. Keers, Matthew Rice, Kira L. F. Hilton, Hiral A. Kotak, J. Mark Sutton, Jose L. Ortega-Roldan, Charlotte K. Hind, Jennifer R. Hiscock, Cally J. E. Haynes
A new Workflow rapidly identifies biologically relevant ion transport and membrane rupture processes in vesicles of different membrane compositions. The Workflow enabled the identification of promising antimicrobials from compound libraries.
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Going full circle: dynamic covalent enzyme immobilisation via visually trackable boronate esters

Chem. Sci., 2026, 17,8513-8520
DOI: 10.1039/D5SC08585C, Edge Article

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This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Glenn Bojanov, Juliette Swit, Francesca Paradisi
Alizarin-IDA as binding handle and colourimetric process reporter for reversible boronate-ester immobilisation of structurally diverse enzymes. Supports are fully regenerated across 5 enzyme lifecycles, delivering 50+ catalytic cycles per carrier.
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Realizing luminescent single crystals of covalent organic polymers with color-tunable emission through isomer engineering

Chem. Sci., 2026, 17,8662-8669
DOI: 10.1039/D5SC09875K, Edge Article

Open Access

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Yanyan Qin, Pengfei She, Xiaoda Wang, Jianjun Wu, Mingbing Lian, Feiyang Li, Shujuan Liu, Qianfeng Gu, Yun Ma, Qiang Zhao, Qichun Zhang
Luminescent B–N linked polymer single crystals have been successfully synthesized through a molecular isomer engineering strategy. Moreover, advanced information encryption and optical storage applications have been developed.
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Accurate prediction of cucurbituril binding affinities from guest molecular formulae

Chem. Sci., 2026, 17,8712-8718
DOI: 10.1039/D6SC00680A, Edge Article

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Josie Franks, Eric Masson
Three empirical models were developed to predict in mere seconds the binding affinities of 39 loose-fitting guests to Cucurbit[7]uril without ever invoking the macrocycle.
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Three reversibly interconvertible redox states of boradigermaallyl: syntheses of radical allyl anion and allyl dianion

Chem. Sci., 2026, 17,8622-8629
DOI: 10.1039/D6SC00727A, Edge Article

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Stefan F. Miehe, Klaus Eichele, Hartmut Schubert, Holger F. Bettinger, Christian P. Sindlinger, Lars Wesemann
Radical anion and dianion were characterized as products of a reversible stepwise two-electron reduction of boradigermaallyl.
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